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Cas Database |
| Name |
(S)-Oxiranemethanol |
EINECS | N/A |
| CAS No. | 60456-23-7 | Density | 1.116 g/mL at 20 °C(lit.) |
| PSA | 32.76000 | LogP | -0.62250 |
| Solubility | N/A | Melting Point |
72-73 °C |
| Formula | C3H6O2 | Boiling Point | 162.4 °C at 760 mmHg |
| Molecular Weight | 74.0794 | Flash Point | 81.1 °C |
| Transport Information | UN 2810 6.1/PG 2 | Appearance | Colorless to light yellow liquid |
| Safety | 53-45-36/37/39-26 | Risk Codes | 45-60-21/22-23-36/37/38-68-41-37/38 |
| Molecular Structure |
|
Hazard Symbols |
|
| Synonyms |
Oxiranemethanol,(2S)- (9CI);Oxiranemethanol, (S)-;(-)-2,3-Epoxy-1-propanol;(-)-D-Glycidol;(-)-Glycidol;(2S)-2-Oxiranylmethanol;(S)-(-)-Glycidol;(S)-(-)-Oxiranemethanol;(S)-Glycidol;(S)-Oxiran-2-ylmethanol;S-Glycidylalcohol; |
Article Data | 33 |
(S)-Oxiranemethanol Synthetic route
- 1613271-06-9
(R)-oxiran-2-ylmethyl 3,5-dinitrobenzoate
- 60456-23-7
(S)-oxiranemethanol
Conditions
| Conditions | Yield |
|---|---|
| With methanol for 2h; Inert atmosphere; Reflux; | 92% |
| In methanol for 2h; Reflux; Inert atmosphere; | 92% |
- 107-18-6
allyl alcohol
- 60456-23-7
(S)-oxiranemethanol
Conditions
| Conditions | Yield |
|---|---|
| With L-(+)-diisopropyl tartrate; Cumene hydroperoxide; titanium(IV) isopropylate In dichloromethane at 0℃; for 48h; Product distribution / selectivity; Molecular sieve; | 72% |
| With tert.-butylhydroperoxide; L-(+)-diisopropyl tartrate; ((CH3)3CCH2)3Ta=CHC(CH3)3 impergnated on silica (pretreated with HMDS) In dichloromethane at 0℃; for 48h; Product distribution / selectivity; | 65% |
| With tert.-butylhydroperoxide; L-(+)-diisopropyl tartrate; ((CH3)3CCH2)3Ta=CHC(CH3)3 impergnated on silica; tantal content 5.63percent (C/Ta=8.0) In dichloromethane at 0℃; for 48h; Product distribution / selectivity; | 61% |
- 60827-45-4
(S)-3-chloropropan-1,2-diol
- 60456-23-7
(S)-oxiranemethanol
Conditions
| Conditions | Yield |
|---|---|
| With potassium carbonate In dichloromethane at 20℃; for 20h; | 72% |
| With potassium carbonate | |
| With potassium phosphate In dichloromethane for 3h; Product distribution / selectivity; Heating / reflux; |
- 98760-25-9, 120787-40-8, 121787-43-7, 13443-29-3
oxiran-2-ylmethyl benzoate
A
- 60456-23-7
(S)-oxiranemethanol
B
- 120787-40-8
(R)-2,3-epoxypropyl benzoate
Conditions
| Conditions | Yield |
|---|---|
| With lipasePS-C In tetrahydrofuran; water for 17h; Ambient temperature; | A 46% B n/a |
Conditions
| Conditions | Yield |
|---|---|
| With tert.-butylhydroperoxide; L-(+)-diisopropyl tartrate; tantalum pentaethoxide In dichloromethane at 0℃; for 48h; Product distribution / selectivity; Molecular sieve; | A 45% B n/a |
| With Cumene hydroperoxide; 3 A molecular sieve; titanium(IV) isopropylate; D-(-)-diisopropyl tartrate In dichloromethane at -5℃; for 6h; Title compound not separated from byproducts; | |
| With titanium(IV) isopropylate; L-(+)-diisopropyl tartrate; Cumene hydroperoxide 1.) CH2Cl2, -10 deg C, 20 min, 2.) CH2Cl2, -10 deg C, 5 h; Yield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts; |
Conditions
| Conditions | Yield |
|---|---|
| With water; (R,R)-[Co(salen)]2*GaCl3 In tetrahydrofuran at 20℃; for 7h; | A n/a B 43% |
- 556-52-5
oxiranyl-methanol
A
- 56-81-5
glycerol
B
- 57044-25-4
(R)-oxiranemethanol
C
- 60456-23-7
(S)-oxiranemethanol
Conditions
| Conditions | Yield |
|---|---|
| With water; dimeric chiral (salen)Co complex linked with Al at 20℃; for 4h; Product distribution; Further Variations:; Catalysts; | A 42% B n/a C n/a |
- 4704-77-2
1-bromo-2,3-propanediol
- 60456-23-7
(S)-oxiranemethanol
Conditions
| Conditions | Yield |
|---|---|
| With potassium hydroxide |
- 50765-70-3
(S)-1-tosyloxy-2,3-propanediol
- 60456-23-7
(S)-oxiranemethanol
Conditions
| Conditions | Yield |
|---|---|
| With sodium methylate In methanol |
- 24553-03-5
phenylacetate of 2,3-epoxypropan-1-ol
A
- 57044-25-4
(R)-oxiranemethanol
B
- 60456-23-7
(S)-oxiranemethanol
Conditions
| Conditions | Yield |
|---|---|
| With immobilized penicillinacylase from E. coli In water; acetonitrile Ambient temperature; stopped at 50percent conversion; |
(S)-Oxiranemethanol Chemical Properties
MF: C3H6O2
Synonyms: RARECHEM AK HZ 0047;(S)-(-)-2,3-EPOXY-1-PROPANOL;(S)-(-)-GLYCIDOL;(S)-GLYCIDOL;(S)-Oxiranemethanol;S(-)-OXIRANE-2-METHANOL;OXIRANEMETHANOL, (2S)-;(s)-oxiranemethano
MW: 74.08
Appearance: Colorless to light yellow liqui
alpha: -15 o (neat)
bp: 66-67 °C19 mm Hg(lit.)
density: 1.116 g/mL at 20 °C(lit.)
refractive index: n20/D 1.433(lit.)
Fp: 178 °F
storage temp.: -20°C
Synonyms: RARECHEM AK HZ 0047;(S)-(-)-2,3-EPOXY-1-PROPANOL;(S)-(-)-GLYCIDOL;(S)-GLYCIDOL;(S)-Oxiranemethanol;S(-)-OXIRANE-2-METHANOL;OXIRANEMETHANOL, (2S)-;(s)-oxiranemethano
MW: 74.08
Appearance: Colorless to light yellow liqui
alpha: -15 o (neat)
bp: 66-67 °C19 mm Hg(lit.)
density: 1.116 g/mL at 20 °C(lit.)
refractive index: n20/D 1.433(lit.)
Fp: 178 °F
storage temp.: -20°C
(S)-Oxiranemethanol Safety Profile
Risk Statements: 45-60-21/22-23-36/37/38-68-41-37/38
Safety Statements: 53-45-36/37/39-26
Hazard Codes: T
RIDADR: UN 2810 6.1/PG 2
RTECS: RR0508100
Safety Statements: 53-45-36/37/39-26
Hazard Codes: T
RIDADR: UN 2810 6.1/PG 2
RTECS: RR0508100
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