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| Name |
1,2,4-Butanetriol trinitrate |
EINECS | 229-697-1 |
| CAS No. | 6659-60-5 | Density | 1.582 g/cm3 |
| PSA | 165.15000 | LogP | 0.93960 |
| Solubility | N/A | Melting Point |
N/A |
| Formula | C4H7 N3 O9 | Boiling Point | 334.4 °C at 760 mmHg |
| Molecular Weight | 241.114 | Flash Point | 162.4 °C |
| Transport Information | N/A | Appearance | N/A |
| Safety | An explosive. When heated to decomposition it emits toxic vapors of NOx. | Risk Codes | 11-20/21/22-36 |
| Molecular Structure |
|
Hazard Symbols | F,Xn |
| Synonyms |
1,2,4-Butanetriol,trinitrate (8CI,9CI); 1,2,4-Butanetriyl nitrate (6CI,7CI); BTTN |
1,2,4-Butanetriol trinitrate Synthetic route
| Conditions | Yield |
|---|---|
| With ammonium nitrate; sulfuric acid at 15℃; for 3h; Cooling with ice; | 80% |
| With sulfuric acid; nitric acid | |
| With sulfuric acid; nitric acid at -10 - 10℃; |
1,2,4-Butanetriol trinitrate Chemical Properties
IUPAC Name: [3-Nitrooxy-1-(nitrooxymethyl)propyl] nitrate
The MF of 1,2,4-Butanetriol trinitrate (CAS NO.6659-60-5) is C4H7N3O9.
The MW of 1,2,4-Butanetriol trinitrate (CAS NO.6659-60-5) is 241.11.
Synonyms of 1,2,4-Butanetriol trinitrate (CAS NO.6659-60-5): 1,2,4-Butanetriol, trinitrate ; Butane-1,2,4-triyl nitrate
colorless to brown explosive liquid
Index of Refraction: 1.487
EINECS: 229-697-1
Density: 1.582 g/ml
Flash Point: 162.4 °C
Boiling Point: 334.4 °C
1,2,4-Butanetriol trinitrate Uses
1,2,4-Butanetriol trinitrate (CAS NO.6659-60-5) is used as a propellant in virtually all single-stage missiles used by the United States, including the Hellfire. It is less volatile, less sensitive to shock, and more thermally stable than nitroglycerine, for which it is a promising replacement.
BTTN as a propellant is often used in a mixture with nitroglycerin. The mixture can be made by conitration of butanetriol and glycerol. BTTN is also used as a plasticizer in some nitrocellulose based propellants.
1,2,4-Butanetriol trinitrate Production
BTTN is manufactured by nitration of 1,2,4-butanetriol. Biotechnological manufacture of butanetriol is under intensive research.
1,2,4-Butanetriol trinitrate Consensus Reports
Reported in EPA TSCA Inventory.
1,2,4-Butanetriol trinitrate Safety Profile
An explosive. When heated to decomposition it emits toxic vapors of NOx.Safety information of 1,2,4-Butanetriol trinitrate (CAS NO.6659-60-5):
RIDADR 0473
HazardClass 1.1A
1,2,4-Butanetriol trinitrate Standards and Recommendations
DOT Classification: Forbidden
1,2,4-Butanetriol trinitrate Specification
1,2,4-Butanetriol trinitrate (BTTN), also called butanetriol trinitrate, is an important military propellant. It is a colorless to brown explosive liquid.
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