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Name	1,8-Dinitronaphthalene	EINECS	210-016-1
CAS No.	602-38-0	Density	1.481g/cm³
PSA	91.64000	LogP	3.70260
Solubility	0.1 g/100ml AUTOIGNITION	Melting Point		171 - 172 C (97 %)
Formula	C10H6 N2 O4	Boiling Point	389.8°C at 760 mmHg
Molecular Weight	218.169	Flash Point	200.3°C
Transport Information	25kgs	Appearance	Yellow Crystalline Powder
Safety		Risk Codes	11-36/37/38
Molecular Structure		Hazard Symbols	UN NO.
Synonyms	1,8-Dinitronaphthalene;NSC 6323	Article Data	56

1,8-Dinitronaphthalene Synthetic route

: 518-05-8
Naphthalene-1,8-dicarboxylic acid

: 602-38-0
1,8-dinitronaphthalene

Conditions

Conditions	Yield
With nitronium tetrafluoborate; silver carbonate In N,N-dimethyl acetamide at 90℃; for 12h; Inert atmosphere; Schlenk technique; regioselective reaction;	81%

: 91-20-3
naphthalene

A: 86-57-7
1-Nitronaphthalene

B: 602-38-0
1,8-dinitronaphthalene

C: 605-71-0
1,5-dinitronaphthalene

Conditions

Conditions	Yield
With nitric acid at 64.84℃; for 3h; Catalytic behavior; Reagent/catalyst;	A 78.5% B 10.6% C 6.2%
With nitric acid In acetic acid at 64.84℃; for 3h; Catalytic behavior; Solvent;	A 22.5% B 42.5% C 32.6%
With phosphotungstic acid; nitric acid at 64.84℃; for 3h; Catalytic behavior; Reagent/catalyst;	A 31.5% B 36.7% C 28.5%
With nitric acid In dichloromethane for 12h; Reflux; regioselective reaction;

: 91-20-3
naphthalene

A: 602-38-0
1,8-dinitronaphthalene

B: 605-71-0
1,5-dinitronaphthalene

Conditions

Conditions	Yield
With nitric acid at 64.84℃; for 3h; Catalytic behavior; Reagent/catalyst;	A 49.2% B 48.5%
With nitric acid
With nitric acid Erwaermen des Reaktionsgemischs mit konz. Schwefelsaeure;

: 91-20-3
naphthalene

: 602-38-0
1,8-dinitronaphthalene

Conditions

Conditions	Yield
With sulfuric acid; nitric acid
With Nitrogen dioxide

: 86-57-7
1-Nitronaphthalene

: 602-38-0
1,8-dinitronaphthalene

Conditions

Conditions	Yield
With sulfuric acid; potassium nitrate at 0℃;
With sulfuric acid; nitric acid at 0 - 35℃;
With sulfuric acid; nitric acid

: 86-57-7
1-Nitronaphthalene

A: 602-38-0
1,8-dinitronaphthalene

B: 605-71-0
1,5-dinitronaphthalene

Conditions

Conditions	Yield
With nitric acid
With sulfuric acid; nitric acid at 0℃; Trennung der beiden Isomere durch Umkrystallisieren aus Pyridin;
With sulfuric acid; nitric acid at 0℃;

: 90765-71-2
1-amino-4,5-dinitronaphthalene

: 602-38-0
1,8-dinitronaphthalene

Conditions

Conditions	Yield
With sulfuric acid; acetic acid Diazotization.Behandlung der Diazoniumsalz-Loesung mit Cu2O und Aethanol;

: 99972-07-3
4,5-dinitro-[1]naphthoic acid

: 142-71-2
copper diacetate

: 602-38-0
1,8-dinitronaphthalene

: 91-20-3
naphthalene

A: 602-38-0
1,8-dinitronaphthalene

B: 24824-25-7
1,7‑dinitronaphthalene

C: 607-46-5
1,6-dinitronaphthalene

D: 605-71-0
1,5-dinitronaphthalene

Conditions

Conditions	Yield
With cupric nitrate trihydrate supported on K 10 montmorillonite clay; nitric acid; acetic anhydride In tetrachloromethane for 3h; Ambient temperature; Yield given. Yields of byproduct given;

: 91-20-3
naphthalene

A: 86-57-7
1-Nitronaphthalene

B: 602-38-0
1,8-dinitronaphthalene

C: 606-37-1
2,4-dinitronaphthalene

D: 581-89-5
2-nitronaphthalene

E: 605-71-0
1,5-dinitronaphthalene

Conditions

Conditions	Yield
With Nitrogen dioxide; ozone In dichloromethane at -25℃; for 0.0833333h; Product distribution; Mechanism; other methylnaphthalenes; also with HNO3/Ac2O system and with methanesulfonic acid; var. temp. and reaction times;

...Expand

1,8-Dinitronaphthalene Chemical Properties

Chemical Name: 1,8-Dinitronaphthalene
IUPAC NAME: 1,8-Dinitronaphthalene
CAS No.: 602-38-0
EINECS: 210-016-1
RTECS: QJ4552000
RTECS Class: Mutagen
Molecular Formula: C₁₀H₆N₂O₄
Molecular Weight: 218.17 g/mol
Melting Point: 161 °C
Density: 1.481 g/cm³
Flash Point: 200.3 °C
Boiling Point: 389.8 °C at 760 mmHg
Following is the structure of 1,8-Dinitronaphthalene (CAS No.602-38-0):

The chemical synonymous of 1,8-Dinitronaphthalene (CAS No.602-38-0) are 1,8-Dinitro-Naphthalen ; 1,8-Dinitronaphthalene ; Labotest-Bb Lt00436938 ; 1,8-Dinitronaphthalene, Contains Variable Amounts Of Water, 97% ; Naphthalene, 1,8-Dinitro- ; 1,8-Dinitronaphthalene,85%

1,8-Dinitronaphthalene Toxicity Data With Reference

mmo-sat 100 µg/plate

MUREAV Mutation Research. 91 (1981),321.

1,8-Dinitronaphthalene Consensus Reports

Reported in EPA TSCA Inventory.

1,8-Dinitronaphthalene Safety Profile

Suspected carcinogen. Mutation data reported. When heated to decomposition it emits toxic vapors of NO_x.
Attention:
1. Storage: Store in a cool, dry place. Store in a tightly closed container.
2. Handling: Use spark-proof tools and explosion proof equipment. Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.

1,8-Dinitronaphthalene Standards and Recommendations

DFG MAK: Confirmed Animal Carcinogen with Unknown Relevance to Humans