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1-Cyclohexylethanol
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Name

1-Cyclohexylethanol

 EINECS 214-780-7
CAS No. 1193-81-3 Density 0.928 g/mL at 25 °C(lit.)
PSA 20.23000 LogP 1.94750
Solubility 5.163g/L at 24℃ Melting Point 140 °C
Formula C8H16O Boiling Point 189 °C(lit.)
Molecular Weight 128.214 Flash Point 163 °F
Transport Information N/A Appearance N/A
Safety 23-24/25 Risk Codes 36/37/38
Molecular Structure Molecular Structure of 1193-81-3 (1-Cyclohexylethanol) Hazard Symbols N/A
Synonyms

(1-Hydroxyethyl)cyclohexane;1-Cyclohexane-1-ethanol;1-Cyclohexyl-1-ethanol;Cyclohexylmethylcarbinol;Ethanol, 1-cyclohexyl-;Methanol, cyclohexylmethyl-;Methylcyclohexylcarbinol;Methylcyclohexylmethanol;NSC 44898;NSC 9476;Surflot 944;a-Methylcyclohexanemethanol;

Article Data 202

1-Cyclohexylethanol Synthetic route

98-86-2

acetophenone

1193-81-3

rac-1-cyclohexylethanol

Conditions
ConditionsYield
With hydrogen In water at 100℃; under 15001.5 Torr; for 0.333333h;100%
With ruthenium nanoparticles at 120℃; under 90009 Torr; for 2h; Ionic liquid; Autoclave;99%
With ruthenium; hydrogen In water at 30℃; under 22801.5 Torr; for 12h; Autoclave;94%
823-76-7

Cyclohexyl methyl ketone

1193-81-3

rac-1-cyclohexylethanol

Conditions
ConditionsYield
Stage #1: Cyclohexyl methyl ketone With formic acid; tricarbonyl (4S,7S)-4,7-bis(benzyloxy)-1,3-diphenyl-4,5,6,7-tetrahydro-2H-inden-2-one iron; triethylamine for 0.166667h; Inert atmosphere;
Stage #2: With trimethylamine-N-oxide at 60℃; for 48h; Reagent/catalyst; Concentration; Temperature;		97%
With sodium isopropylate; isopropyl alcohol; ruthenium complex C38H42N2O4P2Ru for 5h; Catalytic hydrogenation; Catalytic transfer hydrogenation;91%
With methanol; sodium tetrahydroborate at 0 - 20℃; for 0.666667h; Inert atmosphere;88%

tert-Butyl-(1-cyclohexyl-ethoxy)-dimethyl-silane

1193-81-3

rac-1-cyclohexylethanol

Conditions
ConditionsYield
With water; scandium tris(trifluoromethanesulfonate) In acetonitrile for 4h; Ambient temperature;97%
2747-38-8

methyltrichlorotitanium

108-94-1

cyclohexanone

A

590-67-0

1-Methylcyclohexanol

B

1193-81-3

rac-1-cyclohexylethanol

Conditions
ConditionsYield
With Methyltitantrichlorid,Triphenylphosphin; cyclohexanecarbaldehyde In dichloromethane at -25℃; for 6h; Product distribution; other phosphane-complexes and reagents;A 95%
B 3%
108-94-1

cyclohexanone

MeTiCl3

MeTiCl3

A

590-67-0

1-Methylcyclohexanol

B

1193-81-3

rac-1-cyclohexylethanol

Conditions
ConditionsYield
With Methyltitantrichlorid,Triphenylphosphin; cyclohexanecarbaldehyde In dichloromethane at 0℃; for 6h;A 95%
B 3%
17328-74-4

2-methyl-1-oxaspiro[2.5]octane

A

1940-18-7

1-ethylcyclohexanol

B

1193-81-3

rac-1-cyclohexylethanol

C

1-(1-chlorocyclohexyl)ethanol

Conditions
ConditionsYield
With bis(cyclopentadienyl)titanium (III) chloride; cyclohexa-1,4-diene In tetrahydrofuran Product distribution; Mechanism; Ambient temperature; other epoxides, reaction without cyclohexa-1,4-diene;A 1.5%
B 92%
C 0.9%
With bis(cyclopentadienyl)titanium (III) chloride; cyclohexa-1,4-diene In tetrahydrofuran Ambient temperature;A 1.5%
B 92%
C 0.9%
With bis(cyclopentadienyl)titanium (III) chloride; cyclohexa-1,4-diene In tetrahydrofuran for 0.666667h; Product distribution; Mechanism; other epoxides; other H-atom donors; var. temperature, var. time;A 1.5%
B 64%
C 0.9%
With bis(cyclopentadienyl)titanium (III) chloride; cyclohexa-1,4-diene In tetrahydrofuran for 0.25h;A n/a
B 64%
C 0.9%
With bis(cyclopentadienyl)titanium (III) chloride; cyclohexa-1,4-diene In tetrahydrofuran for 0.25h; Yields of byproduct given;A n/a
B n/a
C 0.9%
145804-82-6

2-(2,6-dimethoxyphenoxy)-1-phenylethan-1-ol

A

91-10-1

1,3-dimethoxy-2-hydroxy-benzene

B

100-41-4

ethylbenzene

C

1193-81-3

rac-1-cyclohexylethanol

Conditions
ConditionsYield
With Ni0.85Ru0.15; hydrogen In water at 95℃; under 760.051 Torr; for 16h; Reagent/catalyst;A 92%
B 58%
C 22%

(1-cyclohexylethoxy)trimethylsilane

1193-81-3

rac-1-cyclohexylethanol

Conditions
ConditionsYield
With water; boric acid at 20℃; for 1h;90%
2747-38-8

methyltrichlorotitanium

2043-61-0

cyclohexanecarbaldehyde

A

591-78-6

n-hexan-2-one

B

1193-81-3

rac-1-cyclohexylethanol

Conditions
ConditionsYield
With n-hexan-2-one; Methyltitantrichlorid,Triphenylphosphin In dichloromethane at -25℃; for 6h; Product distribution; other phosphane-complexes and reagents;A 6%
B 89%
2043-61-0

cyclohexanecarbaldehyde

MeTiCl3

MeTiCl3

A

590-67-0

1-Methylcyclohexanol

B

1193-81-3

rac-1-cyclohexylethanol

Conditions
ConditionsYield
With n-hexan-2-one; Methyltitantrichlorid,Triphenylphosphin In dichloromethane at -25℃; for 6h;A 6%
B 89%

1-Cyclohexylethanol Chemical Properties

Chemical Name: 1-Cyclohexylethanol
IUPAC NAME: 1-Cyclohexylethanol
CAS No.: 1193-81-3
EINECS: 214-780-7
RTECS: GV5776500
RTECS Class: Primary Irritant
Molecular Formula: C8H16O
Molecular Weight: 128.21 g/mol
Density: 0.884 g/cm3
Flash Point: 80.2 °C
Boiling Point: 192 °C at 760 mmHg
Following is the structure of 1-Cyclohexylethanol (CAS No.1193-81-3):


The chemical synonymous of 1-Cyclohexylethanol (CAS No.1193-81-3) are (R,S)-1-Cyclohexyl-ethanol ; 1-Cyclohexyl-1-ethanol ; 2-Methylcyclohexylmethanol ; alpha-Methyl-cyclohexanemethano ; Cyclohexanemethanol, alpha-methyl- ; Ethanol, 1-cyclohexyl- ; Methanol, cyclohexylmethyl- ; Methylcyclohexylcarbinol

1-Cyclohexylethanol Toxicity Data With Reference

1.    

skn-rbt 500 µL/24H SEV

     NTIS**    National Technical Information Service. (Springfield, VA 22161) (Formerly U.S. Clearinghouse for Scientific and Technical Information) OTS0545755 .
2.    

eye-rbt 100 µL/24H MLD

     NTIS**    National Technical Information Service. (Springfield, VA 22161) (Formerly U.S. Clearinghouse for Scientific and Technical Information) OTS0545755 .
3.    

orl-rat LD50:2100 mg/kg

     NTIS**    National Technical Information Service. (Springfield, VA 22161) (Formerly U.S. Clearinghouse for Scientific and Technical Information) OTS0545755 .
4.    

skn-rbt LDLo:1 g/kg

     NTIS**    National Technical Information Service. (Springfield, VA 22161) (Formerly U.S. Clearinghouse for Scientific and Technical Information) OTS0545755 .

1-Cyclohexylethanol Safety Profile

Moderately toxic by ingestion and skin contact. A severe skin and mild eye irritant. When heated to decomposition it emits acrid smoke and irritating vapors.
Risk Statements about 1-Cyclohexylethanol (CAS No.1193-81-3):
R36/37/38:Irritating to eyes, respiratory system and skin.
Safety Statements about 1-Cyclohexylethanol (CAS No.1193-81-3):
S23:Do not breathe vapour.
S24/25:Avoid contact with skin and eyes.

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