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Name |
12-Methyltridecanal |
EINECS | N/A |
CAS No. | 75853-49-5 | Density | 0.825 g/cm3 |
PSA | 17.07000 | LogP | 4.74230 |
Solubility | N/A | Melting Point |
25°C (estimate) |
Formula | C14H28O | Boiling Point | 275.1 ºC at 760 mmHg |
Molecular Weight | 212.376 | Flash Point | 111.5 ºC |
Transport Information | N/A | Appearance | Almost colourless to very slightly yellow |
Safety | Risk Codes | N/A | |
Molecular Structure | Hazard Symbols | N/A | |
Synonyms |
12-Methyltridecanal;12-Methyl tridecanal; |
Article Data | 11 |
12-methyl-1-tridecanol
12-methyltridecan-1-al
Conditions | Yield |
---|---|
With pyridinium chlorochromate In dichloromethane at 20℃; for 24h; | 98% |
With oxalyl dichloride; dimethyl sulfoxide; triethylamine In dichloromethane at -78 - 0℃; for 4h; | 85% |
With pyridinium chlorochromate In dichloromethane for 2h; | 84% |
With dipyridinium dichromate; 3 A molecular sieve In dichloromethane for 2h; Ambient temperature; | |
With Dess-Martin periodane In dichloromethane at 20℃; for 1h; |
13-methyltetradec-1-ene
12-methyltridecan-1-al
Conditions | Yield |
---|---|
With ozone In dichloromethane at -55℃; Temperature; | 93.5% |
1,2-epoxy-13-methyltetradecane
12-methyltridecan-1-al
Conditions | Yield |
---|---|
With periodic acid In tetrahydrofuran; diethyl ether for 4h; | 66.04% |
methyl 12-methyltridecanoate
12-methyltridecan-1-al
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: 93 percent / LiAlH4 / diethyl ether / 2 h / 0 °C 2: 98 percent / pyridinium chlorochromate / CH2Cl2 / 24 h / 20 °C View Scheme |
1-undecen-11-ylbromide
12-methyltridecan-1-al
Conditions | Yield |
---|---|
Multi-step reaction with 3 steps 1: 1.) Mg, 2.) dilithium tetrachlorocuprate / 1) THF, 2.) THF, -10 deg C, 4 h 2: 1.) NaBH4, Hg(OAc)2, 2.) aq. H2O2, aq. NaOH / 1) THF, 16 h, room temperature; 2) THF, 70 deg C, 1 h 3: 84 percent / pyridinium chlorochromate / CH2Cl2 / 2 h View Scheme |
12-methyltridec-1-ene
12-methyltridecan-1-al
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: 1.) NaBH4, Hg(OAc)2, 2.) aq. H2O2, aq. NaOH / 1) THF, 16 h, room temperature; 2) THF, 70 deg C, 1 h 2: 84 percent / pyridinium chlorochromate / CH2Cl2 / 2 h View Scheme |
ethyl 12-methyltridecanoate
12-methyltridecan-1-al
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: 100 percent / LiAlH4 / tetrahydrofuran 2: pyridinium dichromate (PDC), molecular sieves 3A / CH2Cl2 / 2 h / Ambient temperature View Scheme |
ethyl E-12-methyltridec-2-enoate
12-methyltridecan-1-al
Conditions | Yield |
---|---|
Multi-step reaction with 3 steps 1: 74 percent / H2 / 10percent Pd/C / ethanol / Ambient temperature 2: 100 percent / LiAlH4 / tetrahydrofuran 3: pyridinium dichromate (PDC), molecular sieves 3A / CH2Cl2 / 2 h / Ambient temperature View Scheme |
1,10-Decanediol
12-methyltridecan-1-al
Conditions | Yield |
---|---|
Multi-step reaction with 3 steps 1: hydrogen bromide / water; toluene / 48 h / Reflux 2: dilithium tetrachlorocuprate / tetrahydrofuran / 20 h / -78 °C 3: oxalyl dichloride; dimethyl sulfoxide; triethylamine / dichloromethane / 4 h / -78 - 0 °C View Scheme |
1-bromo-10-decanol
12-methyltridecan-1-al
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: dilithium tetrachlorocuprate / tetrahydrofuran / 20 h / -78 °C 2: oxalyl dichloride; dimethyl sulfoxide; triethylamine / dichloromethane / 4 h / -78 - 0 °C View Scheme |
Molecular Structure of 12-Methyltridecanal (CAS No.75853-49-5):
Molecular Formula: C14H28O
Molecular Weight: 212.3715
CAS No: 75853-49-5
IUPAC Name: 12-Methyltridecanal
Product Categories: Aldehyde Flavor
H bond acceptors: 1
H bond donors: 0
Freely Rotating Bonds: 11
Polar Surface Area: 17.07 Å2
Index of Refraction: 1.434
Molar Refractivity: 67.05 cm3
Molar Volume: 257.3 cm3
Surface Tension: 28.6 dyne/cm
Density: 0.825 g/cm3
Flash Point: 111.5 °C
Enthalpy of Vaporization: 51.35 kJ/mol
Boiling Point: 275.1 °C at 760 mmHg
Vapour Pressure: 0.0052 mmHg at 25°C
InChI: InChI=1/C14H28O/c1-14(2)12-10-8-6-4-3-5-7-9-11-13-15/h13-14H,3-12H2,1-2H3
InChIKey: OQWNKUAZQSLNSR-UHFFFAOYAC
Std. InChI: InChI=1S/C14H28O/c1-14(2)12-10-8-6-4-3-5-7-9-11-13-15/h13-14H,3-12H2,1-2H3
Std. InChIKey: OQWNKUAZQSLNSR-UHFFFAOYSA-N
12-Methyltridecanal (CAS No.75853-49-5), its synonyms are Tridecanal, 12-methyl- ; 12-MT Aldehyde .