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2,3-Diamino-2,3-dimethylbutane

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Name

2,3-Diamino-2,3-dimethylbutane

EINECS N/A
CAS No. 20485-44-3 Density 0.86 g/cm3
PSA 52.04000 LogP 1.86160
Solubility N/A Melting Point 97-98 °C
Formula C6H16N2 Boiling Point 157.2 °C at 760 mmHg
Molecular Weight 116.206 Flash Point 43.4 °C
Transport Information N/A Appearance N/A
Safety Risk Codes N/A
Molecular Structure Molecular Structure of 20485-44-3 (2,3-Diamino-2,3-dimethylbutane) Hazard Symbols N/A
Synonyms

Tetramethylethylendiamine;2,3-Dimethylbutane-2,3-diamine;2,3-Butanediamine, 2,3-dimethyl-;

Article Data 17

2,3-Diamino-2,3-dimethylbutane Synthetic route

3964-18-9

2,3-dimethyl-2,3-dinitrobutane

20485-44-3

2,3-dimethyl-2,3-diaminobutane

Conditions
ConditionsYield
With hydrogenchloride; tin for 3h; Heating;81%
With hydrogenchloride; tin75%
With hydrogenchloride; tin In water at 105℃; for 4h;60%
563-79-1

2,3-Dimethyl-2-butene

20485-44-3

2,3-dimethyl-2,3-diaminobutane

Conditions
ConditionsYield
With lithium aluminium tetrahydride; 2; nitrogen(II) oxide 1) THF, 0 deg C, 85 min; 2) THF, -70 deg C, room temperature (overnight), reflux (1 h); Yield given. Multistep reaction;
Multi-step reaction with 2 steps
1: diethyl ether; dinitrogen tetraoxide / -20 - -16 °C
2: platinum; glacial acetic acid / Hydrogenation
View Scheme
75-31-0

isopropylamine

20485-44-3

2,3-dimethyl-2,3-diaminobutane

131611-95-5

{Co(tmen)3}(3+)

A

20485-44-3

2,3-dimethyl-2,3-diaminobutane

B

cobalt(II)

Conditions
ConditionsYield
With V(2+)aq. In perchloric acid Kinetics; reduction with V(2+)aq. at 25°C in 1M HClO4; monitored spectrophotometrically;
With Cr(2+)aq. In further solvent(s) Kinetics; reduction with Cr(2+)aq. at 25°C in 1M CF3SO3Na + 0.1M CF3SO3H; monitored spectrophotometrically;
With Eu(2+)aq. In perchloric acid Kinetics; redution with Eu(2+)aq. at 25°C in 1M HClO4; monitored spectrophotometrically;
131611-95-5

{Co(tmen)3}(3+)

A

20485-44-3

2,3-dimethyl-2,3-diaminobutane

B

cobalt(II)

Conditions
ConditionsYield
In further solvent(s) Kinetics; reduction at 25°C in 0.2 M NaCl; monitored spectrophotometrically;
131611-95-5

{Co(tmen)3}(3+)

30251-71-9

hexaaquaruthenium(II)

A

20485-44-3

2,3-dimethyl-2,3-diaminobutane

B

cobalt(II)

Conditions
ConditionsYield
In further solvent(s) Kinetics; at 25°C in 1M CF3SO3Na + 0.1M CF3SO3H; monitored spectrophotometrically;
20485-44-3

2,3-dimethyl-2,3-diaminobutane

100-52-7

benzaldehyde

351902-03-9

2-Phenyl-4,4,5,5-tetramethylimidazolidine

Conditions
ConditionsYield
In diethyl ether ice cooling;99%

butyl-hydroxy-toluene

20485-44-3

2,3-dimethyl-2,3-diaminobutane

6900-35-2

potassium methacrylate

104-83-6

1-Chloro-4-(chloromethyl)benzene

Conditions
ConditionsYield
In toluene98.2%

20485-44-3

2,3-dimethyl-2,3-diaminobutane

6900-35-2

potassium methacrylate

Conditions
ConditionsYield
In toluene97.4%
2,3-dimethyl-2,3-diaminobutane

2,3-dimethyl-2,3-diaminobutane

90-02-8

salicylaldehyde

60306-02-7

N,N'-(1,1,2,2-tetramethylethylene)bis(salicylideneimine)

Conditions
ConditionsYield
96%
With ethanol

2,3-Diamino-2,3-dimethylbutane Specification

The 2,3-Diamino-2,3-dimethylbutane, with the CAS registry number 20485-44-3, is also known as Tetramethylethylendiamine. This chemical's molecular formula is C6H16N2 and molecular weight is 116.2. What's more, its systematic name is 2,3-dimethylbutane-2,3-diamine. 

Physical properties of 2,3-Diamino-2,3-dimethylbutane are: (1)ACD/LogP: -0.65; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): -4.62; (4)ACD/LogD (pH 7.4): -3.3; (5)ACD/BCF (pH 5.5): 1; (6)ACD/BCF (pH 7.4): 1; (7)ACD/KOC (pH 5.5): 1; (8)ACD/KOC (pH 7.4): 1; (9)#H bond acceptors: 2; (10)#H bond donors: 4; (11)#Freely Rotating Bonds: 3; (12)Polar Surface Area: 6.48 Å2; (13)Index of Refraction: 1.458; (14)Molar Refractivity: 36.84 cm3; (15)Molar Volume: 135 cm3; (16)Polarizability: 14.6×10-24cm3; (17)Surface Tension: 31.1 dyne/cm; (18)Density: 0.86 g/cm3; (19)Flash Point: 43.4 °C; (20)Enthalpy of Vaporization: 39.39 kJ/mol; (21)Boiling Point: 157.2 °C at 760 mmHg; (22)Vapour Pressure: 2.79 mmHg at 25°C.

Preparation of 2,3-Diamino-2,3-dimethylbutane: this chemical can be prepared by 2,3-dimethyl-2,3-dinitro-butane by heating. This reaction will need reagents Sn, aq. HCl with the reaction time of 3 hours. The yield is about 81%.

2,3-Diamino-2,3-dimethylbutane can be prepared by 2,3-dimethyl-2,3-dinitro-butane by heating

Uses of 2,3-Diamino-2,3-dimethylbutane: it can be used to produce N,N'-Dibenzyliden-tetramethyl-aethylendiamin. It will need reagent molecular sieves with the reaction time of 2 hours. The yield is about 60%.

2,3-Diamino-2,3-dimethylbutane can be used to produce N,N'-Dibenzyliden-tetramethyl-aethylendiamin

You can still convert the following datas into molecular structure:
(1)Canonical SMILES: CC(C)(C(C)(C)N)N
(2)InChI: InChI=1S/C6H16N2/c1-5(2,7)6(3,4)8/h7-8H2,1-4H3
(3)InChIKey: CGCVLTOGUMLHNP-UHFFFAOYSA-N

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