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2,3-Dibromo-1-propanol

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Name

2,3-Dibromo-1-propanol

EINECS 202-480-9
CAS No. 96-13-9 Density 2.129 g/cm3
PSA N/A LogP N/A
Solubility 5-10 g/100 mL at 20 ºC Melting Point 8oC
Formula C3H6Br2O Boiling Point 203.3 °C at 760 mmHg
Molecular Weight 217.888 Flash Point 107 °C
Transport Information UN 2810 6.1/PG 2 Appearance clear colorless liquid
Safety 53-45-61 Risk Codes 45-20/22-24-52/53-62
Molecular Structure Molecular Structure of 96-13-9 (2,3-Dibromo-1-propanol) Hazard Symbols ToxicT
Synonyms

1,2-Dibromopropan-3-ol;2,3-Dibromopropyl alcohol;Brominex 257;DBP(flame retardant);NSC 6203;

Article Data 45

2,3-Dibromo-1-propanol Chemical Properties

Empirical Formula: C3H6Br2
Molecular Weight: 217.8871 
IUPAC Name: 2,3-Dibromopropan-1-ol
Synonyms: Glycerol 1,2-dibromohydrin ; 1,2-Dibromopropan-3-ol ; Beta-dibromohydrin ; 2,3-Dibromo-1-propanol
Boiling Point: 95-97 °C at 10 mm Hg(lit.)
Density of 2,3-Dibromopropanol (96-13-9): 2.12 g/mL at 25 °C(lit.)
Refractive index: n20/D 1.559(lit.)
Flash Point: >230 °F
Water Solubility: 5-10 g/100 mL at 20 ºC
Chemical Properties: 2,3-Dibromopropanol (96-13-9) is a clear colorless to slightly yellow viscous liquid.

2,3-Dibromo-1-propanol Uses

 2,3-Dibromopropanol (96-13-9) is used in organic synthesis as a solvent and flame retardant. It is also used as an intermediate of antidote dimercaprolum, polyurethane foam, unsaturated polyester, phenolic, epoxy resin and polypropylene flame-retardant products.

2,3-Dibromo-1-propanol Production

 2,3-Dibromopropanol (96-13-9) is derived from propylene alcohol and bromine by addition reaction.

2,3-Dibromo-1-propanol Toxicity Data With Reference

1.    

sln-dmg-orl 500 ppm

    ENMUDM    Environmental Mutagenesis. 7 (1985),349.
2.    

trn-dmg-orl 500 ppm

    ENMUDM    Environmental Mutagenesis. 7 (1985),349.
3.    

dnd-rat:oth 1 µmol/L

    CRNGDP    Carcinogenesis. 6 (1985),705.
4.    

otr-ham:emb 500 nmol/L

    CRNGDP    Carcinogenesis. 6 (1985),705.
5.    

msc-ham:lng 20 µmol/L

    MUREAV    Mutation Research. 124 (1983),213.
6.    

ipr-mus LDLo:125 mg/kg

    NTIS**    National Technical Information Service. (Springfield, VA 22161) (Formerly U.S. Clearinghouse for Scientific and Technical Information) AD277-689 .

2,3-Dibromo-1-propanol Consensus Reports

NTP 10th Report on Carcinogens. Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program.

2,3-Dibromo-1-propanol Safety Profile

Confirmed carcinogen. Poison by intraperitoneal route. Mutation data reported. When heated to decomposition it emits toxic fumes of Br. See also BROMIDES.
Hazard Codes: T: Toxic
Risk Statements: 45: May cause cancer
20/22: Harmful by inhalation and if swallowed
24: Toxic in contact with skin
52/53: Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment
62: Possible risk of impaired fertility 
Safety Statements: 53: Avoid exposure - obtain special instruction before use
45: In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)
61: Avoid release to the environment. Refer to special instructions safety data sheet
RIDADR: UN 2810 6.1/PG 2
WGK Germany: 3
RTECS: UB0175000
HazardClass: 6.1(b)
PackingGroup: III

2,3-Dibromo-1-propanol Specification

 2,3-Dibromopropanol (96-13-9) is a clear colorless to slightly yellow viscous liquid. It is soluble in alcohol, ether, benzene, acetone and acetic acid, slightly soluble in water. It is probably combustible and incompatible with strong oxidizers.

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