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Cas Database

Name	2-Chloroanisole	EINECS	212-167-9
CAS No.	766-51-8	Density	1.137 g/cm³
PSA	9.23000	LogP	2.34860
Solubility	0.49g/L(25 oC)	Melting Point	-27oC
Formula	C₇H₇ClO	Boiling Point	198.5 °C at 760 mmHg
Molecular Weight	142.585	Flash Point	70.8 °C
Transport Information	N/A	Appearance	clear light yellow liquid
Safety	24/25	Risk Codes	N/A
Molecular Structure		Hazard Symbols	N/A
Synonyms	Anisole,o-chloro- (6CI,7CI,8CI);1-Chloro-2-methoxybenzene;2-Chloromethoxybenzene;2-Chlorophenol methyl ether;2-Methoxy-1-chlorobenzene;2-Methoxyphenyl chloride;NSC 155175;o-Chloroanisole;o-Chloromethoxybenzene;o-Chlorophenyl methyl ether;o-Methoxychlorobenzene;	Article Data	153

2-Chloroanisole Synthetic route

: 5720-06-9
2-Methoxyphenylboronic acid

: 766-51-8
2-Chloroanisole

Conditions

Conditions	Yield
With N-chloro-succinimide; copper(l) chloride In acetonitrile at 80℃; for 18h;	97%
With N-chloro-succinimide In acetonitrile at 80℃; for 24h;	90%

: 95-57-8
2-monochlorophenol

: 77-78-1
dimethyl sulfate

: 766-51-8
2-Chloroanisole

Conditions

Conditions	Yield
Stage #1: 2-monochlorophenol With potassium carbonate In acetone for 0.25h; Stage #2: dimethyl sulfate In acetone for 10h; Reflux;	96%
With sodium hydroxide In water at 90℃; for 0.5h;	84.6%
With potassium hydroxide at 100℃;
With sodium hydroxide at 100℃;
With lithium hydroxide In tetrahydrofuran for 1h; Ambient temperature; Yield given;

: 100-66-3
methoxybenzene

A: 623-12-1
4-chloromethoxybenzene

B: 766-51-8
2-Chloroanisole

Conditions

Conditions	Yield
With lithium chloride In N,N-dimethyl acetamide at 30℃; Pt anode, graphite cathode, sintered glass diaphragm, 1.3 V vs. SCE, 965 C;	A 95.8% B 2.8%
With aluminum oxide; sodium chlorite; water; manganese(III) acetylacetonate In dichloromethane at 25℃; for 0.583333h; Product distribution; other solvents, inorganic support materials, times and temperatures, also without H2O;	A 85% B 8%
With chlorine; natural kaolinitic clay In tetrachloromethane for 2h; Heating;	A 85% B 9%

: 95-57-8
2-monochlorophenol

: 74-88-4
methyl iodide

: 766-51-8
2-Chloroanisole

Conditions

Conditions	Yield
With sodium carbonate In dichloromethane at 20℃;	95%
With potassium carbonate In N,N-dimethyl-formamide at 20℃; for 16h;	51%
With sodium hydroxide In N,N-dimethyl acetamide at 25℃; Rate constant;
With potassium carbonate at 130℃;

: 578-57-4
2-bromoanisole

: 766-51-8
2-Chloroanisole

Conditions

Conditions	Yield
With nickel dichloride In N,N-dimethyl-formamide at 170℃; for 0.0833333h; microwave irradiation;	94%
With CuCl-alumina In various solvent(s) at 150℃; for 24h;	54 % Chromat.
With hydrogenchloride; (4s,6s)-2,4,5,6-tetra(9H-carbazol-9-yl)isophthalonitrile; oxygen In water; acetonitrile at 25℃; for 1.5h; Irradiation;	53 %Chromat.

: 14503-45-8
3-chloro-4-methoxybenzyl alcohol

: 766-51-8
2-Chloroanisole

Conditions

Conditions	Yield
With chlorobis(cyclooctene)-iridium(I) dimer; 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; lithium chloride In water; 1,3,5-trimethyl-benzene at 170℃; for 18h; Schlenk technique; Inert atmosphere;	91%

: 95-57-8
2-monochlorophenol

: 616-38-6
carbonic acid dimethyl ester

: 766-51-8
2-Chloroanisole

Conditions

Conditions	Yield
With layered double hydroxide - supported L-methionine at 180℃; for 6h; Autoclave; chemoselective reaction;	90%
With 1,8-diazabicyclo[5.4.0]undec-7-ene In N,N-dimethyl-formamide for 0.0583333h; microwave irradiation;	85%
With dimanganese decacarbonyl at 180℃; for 1h;	2%
With leucine intercalated Mg-Al layered double hydorxide at 180℃; for 6h; Autoclave; Green chemistry; chemoselective reaction;	86 %Chromat.

: 14596-60-2
N-chloro-N-(4-methylphenyl)acetamide

: 100-66-3
methoxybenzene

A: 623-12-1
4-chloromethoxybenzene

B: 766-51-8
2-Chloroanisole

C: 18931-78-7
N-(2-chloro-4-methylphenyl)acetamide

D: 103-89-9
4-Methylacetanilide

Conditions

Conditions	Yield
at 110℃; for 12h; Mechanism; Orton Haloaniline Rearrangement; Inert atmosphere; Darkness;	A 82% B n/a C n/a D 87%

...Expand

: 598-99-2
Methyl trichloroacetate

: 95-57-8
2-monochlorophenol

: 766-51-8
2-Chloroanisole

Conditions

Conditions	Yield
With 18-crown-6 ether; potassium carbonate at 150℃; for 2h;	85%

: 2-methoxy-benzenediazonium; tetrachloro cuprate(II)

: 766-51-8
2-Chloroanisole

Conditions

Conditions	Yield
In dimethyl sulfoxide Ambient temperature;	84%

2-Chloroanisole Chemical Properties

The Molecular formula of 2-Chloroanisole(766-51-8): C₇H₇ClO
The Molecular Weight of 2-Chloroanisole(766-51-8): 142.58
The Molecular Structure of 2-Chloroanisole(766-51-8):

EINECS: 212-167-9
Boiling Point: 198.5 °C at 760 mmHg
Flash Point: 70.8 °C
Index of Refraction: 1.515
Molar Refractivity: 37.82 cm³
Molar Volume: 125.3 cm³
Polarizability: 14.99 10^-24 cm³
Surface Tension: 32.6 dyne/cm
Density: 1.137 g/cm³
Enthalpy of Vaporization: 41.69 kJ/mol
Vapour Pressure: 0.506 mmHg at 25°C
BRN: 2042179
IUPAC Name: 1-chloro-2-methoxybenzene
Synonyms: 1-chloro-2-methoxy-benzen;anisole,o-chloro-;benzene,1-chloro-2-methoxy-;2-chloromethoxybenzene;2-Chlorophenol methyl ether;o-Chloromethoxybenzene;o-Chlorophenyl methyl ether; Anisole, o-chloro-;

2-Chloroanisole Safety Profile

The Safety Statements information of 2-Chloroanisole(766-51-8):
24/25: Avoid contact with skin and eyes
WGK Germany: 3

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