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Cas Database |
| Name |
2-Cyaniminothiazolidine |
EINECS | 427-720-1 |
| CAS No. | 26364-65-8 | Density | 1.43 g/cm3 |
| PSA | 73.48000 | LogP | 0.48868 |
| Solubility | N/A | Melting Point |
156-157 °C(Solv: ethanol (64-17-5); water (7732-18-5)) |
| Formula | C4H5N3S | Boiling Point | 227.6 °C at 760 mmHg |
| Molecular Weight | 127.17 | Flash Point | 91.5 °C |
| Transport Information | N/A | Appearance | N/A |
| Safety | Risk Codes | N/A | |
| Molecular Structure |
|
Hazard Symbols | N/A |
| Synonyms |
Cyanamide,(4,5-dihydro-2-thiazolyl)- (9CI);D2,N-Thiazolidinecarbamonitrile (8CI);2-(Cyanoimino)thiazolidine;2-Cyanoimino-1,3-thiazolidine;2-Thiazolidinylidenecyanamide; |
Article Data | 21 |
2-Cyaniminothiazolidine Synthetic route
- 60-23-1
Cysteamine
- 10191-60-3
dimethyl N-cyanodithioiminocarbonate
- 26364-65-8
2-(N-cyanoimino)thiazolidine
| Conditions | Yield |
|---|---|
| In ethanol at 90℃; for 2h; | 100% |
| In ethanol for 3h; Heating / reflux; | 67.1% |
| In ethanol Heating; |
- 156-57-0
2-mercaptoethylamine hydrochloride
- 10191-60-3
dimethyl N-cyanodithioiminocarbonate
- 26364-65-8
2-(N-cyanoimino)thiazolidine
| Conditions | Yield |
|---|---|
| In ethanol for 6h; Heating; | 95% |
| With sodium carbonate In water at 10 - 20℃; for 2h; Product distribution / selectivity; | 93% |
| With sodium hydrogencarbonate In water at 10 - 20℃; for 3h; Product distribution / selectivity; | 92% |
- 127-09-3
sodium acetate
- 132433-56-8
3-Methanesulfonyl-thiazolidin-(2E)-ylidene-cyanamide
A
- 26364-65-8
2-(N-cyanoimino)thiazolidine
| Conditions | Yield |
|---|---|
| In N,N-dimethyl-formamide at 80℃; | A 6% B 85% |
- 71-23-8
propan-1-ol
- 132433-56-8
3-Methanesulfonyl-thiazolidin-(2E)-ylidene-cyanamide
A
- 140483-44-9
3-Propyl-thiazolidin-(2E)-ylidene-cyanamide
B
- 26364-65-8
2-(N-cyanoimino)thiazolidine
| Conditions | Yield |
|---|---|
| With sodium hydride In N,N-dimethyl-formamide at 80℃; | A 83% B 16% |
- 64-17-5
ethanol
- 132433-56-8
3-Methanesulfonyl-thiazolidin-(2E)-ylidene-cyanamide
A
- 97538-34-6
3-Ethyl-thiazolidin-(2E)-ylidene-cyanamide
B
- 26364-65-8
2-(N-cyanoimino)thiazolidine
| Conditions | Yield |
|---|---|
| With sodium hydride In N,N-dimethyl-formamide at 80℃; | A 82% B 13% |
- 132433-56-8
3-Methanesulfonyl-thiazolidin-(2E)-ylidene-cyanamide
- 108-93-0
cyclohexanol
A
- 26364-65-8
2-(N-cyanoimino)thiazolidine
| Conditions | Yield |
|---|---|
| With sodium hydride In N,N-dimethyl-formamide at 80℃; | A 81% B 6% |
- 67-56-1
methanol
- 132433-56-8
3-Methanesulfonyl-thiazolidin-(2E)-ylidene-cyanamide
A
- 97538-33-5
3-Methyl-thiazolidin-(2E)-ylidene-cyanamide
B
- 26364-65-8
2-(N-cyanoimino)thiazolidine
| Conditions | Yield |
|---|---|
| With sodium hydride In N,N-dimethyl-formamide at 80℃; | A 79% B 16% |
| With sodium hydride In N,N-dimethyl-formamide at 80℃; Mechanism; Product distribution; effect of different alcohols; | A 79% B 16% |
- 64-17-5
ethanol
A
- 97538-34-6
3-Ethyl-thiazolidin-(2E)-ylidene-cyanamide
B
- 26364-65-8
2-(N-cyanoimino)thiazolidine
| Conditions | Yield |
|---|---|
| With sodium hydride In N,N-dimethyl-formamide at 80℃; | A 79% B 10% |
- 132433-56-8
3-Methanesulfonyl-thiazolidin-(2E)-ylidene-cyanamide
- 107-92-6
butyric acid
A
- 26364-65-8
2-(N-cyanoimino)thiazolidine
| Conditions | Yield |
|---|---|
| With sodium hydride In N,N-dimethyl-formamide at 80℃; | A 8% B 79% |
- 160314-52-3
3-dimethoxymethyl-2-(N-cyanoimino)thiazolidine
- 100-51-6
benzyl alcohol
A
- 27591-56-6
benzyl formate dimethyl acetal
B
- 26364-65-8
2-(N-cyanoimino)thiazolidine
| Conditions | Yield |
|---|---|
| In tetrahydrofuran Heating; | A 76% B n/a |
2-Cyaniminothiazolidine Chemical Properties
Molecular Structure of 2-Cyaniminothiazolidine (CAS NO.26364-65-8):
.png)
Empirical Formula: C4H5N3S
Molecular Weight: 127.1676
Surface Tension: 63 dyne/cm
Density: 1.43 g/cm3
Flash Point: 91.5 °C
Molar Refractivity: 34.25 cm3
Molar Volume: 88.7 cm3
H bond acceptors: 3
H bond donors: 1
Freely Rotating Bonds: 0
Polar Surface Area: 64.69Å2
Enthalpy of Vaporization: 46.42 kJ/mol
Boiling Point: 227.6 °C at 760 mmHg
Vapour Pressure: 0.0768 mmHg at 25°C
Index of Refraction: 1.698
SMILES: N#CNC/1=N/CCS\1
InChI: InChI=1/C4H5N3S/c5-3-7-4-6-1-2-8-4/h1-2H2,(H,6,7)
Product Categories: Pharmaceutical Intermediates
2-Cyaniminothiazolidine Specification
2-Cyaniminothiazolidine , with CAS number of 26364-65-8, can be called 2-Cyanoimino-1,3-thiazolidine ; 2-Thiazolidinylidenecyanamide ; (2Z)-1,3-Thiazolidin-2-ylidenecyanamide ; 1,3-Thiazolidin-2-ylidenecyanamide ; cyanamide, N-[(2Z)-2-thiazolidinylidene]- ; N-(4,5-Dihydro-2-thiazolyl)cyanamide ; N-(1,3-Thiazolan-2-yliden)cyanamide and so on.
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