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2-Propenoic acid,2,2,3,3-tetrafluoropropyl ester

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Name

2-Propenoic acid,2,2,3,3-tetrafluoropropyl ester

EINECS 230-957-1
CAS No. 7383-71-3 Density 1.254 g/cm3
PSA 26.30000 LogP 1.61600
Solubility Practically insoluble in water Melting Point N/A
Formula C6H6F4O2 Boiling Point 134 °C at 760 mmHg
Molecular Weight 186.106 Flash Point 34.7 °C
Transport Information N/A Appearance N/A
Safety 26-36/37/39 Risk Codes 10-22-37/38-40-41-43
Molecular Structure Molecular Structure of 7383-71-3 (2,2,3,3-TETRAFLUOROPROPYL ACRYLATE) Hazard Symbols HarmfulXn,FlammableF
Synonyms

V 4F;Viscoat 4F;FA 2 (acrylate);R 5210;Tetrafluoropropyl acrylate;2,2,3,3-Tetrafluoropropyl acrylate;1,1,3-Trihydroperfluoropropyl acrylate;1-Propanol,2,2,3,3-tetrafluoro-, acrylate (8CI);Acrylicacid, 2,2,3,3-tetrafluoropropyl ester (7CI,8CI);2,2,3,3-Tetrafluoropropyl prop-2-enoate;

Article Data 3

2-Propenoic acid,2,2,3,3-tetrafluoropropyl ester Synthetic route

76-37-9

2,2,3,3-tetrafluoropropanol

79-10-7

acrylic acid

7383-71-3

acrylate de trihydro-1,1,3 tetrafluoropropyle

Conditions
ConditionsYield
With hydroquinone; sulfonated coal; sulfuric acid In benzene at 80℃; for 10h;34%
With sulfuric acid; hydroquinone In benzene Heating;
10192-85-5

potassium acrylate

110920-07-5

3-[(chlorosulfinyl)oxy]-1,1,2,2-tetrafluoropropane

7383-71-3

acrylate de trihydro-1,1,3 tetrafluoropropyle

Conditions
ConditionsYield
76.2%

2-Propenoic acid,2,2,3,3-tetrafluoropropyl ester Specification

The 2-Propenoic acid,2,2,3,3-tetrafluoropropyl ester, with the CAS registry number 7383-71-3, is also known as 2,2,3,3-Tetrafluoropropyl acrylate. Its EINECS number is 230-957-1. It belongs to the product category of Monomer. This chemical's molecular formula is C6H6F4O2 and molecular weight is 186.1. What's more, its systematic name is 2,2,3,3-Tetrafluoropropyl prop-2-enoate. The product should be sealed and stored in containers which are placed in cool and dry places.

Physical properties of 2-Propenoic acid,2,2,3,3-tetrafluoropropyl ester are: (1)ACD/LogP: 1.48; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): 1.48; (4)ACD/LogD (pH 7.4): 1.48; (5)ACD/BCF (pH 5.5): 7.8; (6)ACD/BCF (pH 7.4): 7.8; (7)ACD/KOC (pH 5.5): 151.45; (8)ACD/KOC (pH 7.4): 151.45; (9)#H bond acceptors: 2; (10)#H bond donors: 0; (11)#Freely Rotating Bonds: 5; (12)Polar Surface Area: 26.3 Å2; (13)Index of Refraction: 1.35; (14)Molar Refractivity: 31.92 cm3; (15)Molar Volume: 148.3 cm3; (16)Polarizability: 12.65×10-24 cm3; (17)Surface Tension: 20.3 dyne/cm; (18)Density: 1.254 g/cm3; (19)Flash Point: 34.7 °C; (20)Enthalpy of Vaporization: 37.15 kJ/mol; (21)Boiling Point: 134 °C at 760 mmHg; (22)Vapour Pressure: 8.25 mmHg at 25°C.

Preparation: this chemical can be prepared by acrylic acid and 2,2,3,3-tetrafluoro-propan-1-ol at the temperature of 80 °C. This reaction will need reagent hydroquinone and solvent benzene with the reaction time of 10 hours. This reaction will also need catalysts H2SO4, sulfonated coal. The yield is about 34%.

2-Propenoic acid,2,2,3,3-tetrafluoropropyl ester can be prepared by acrylic acid and 2,2,3,3-tetrafluoro-propan-1-ol at the temperature of 80 °C

When you are using this chemical, please be cautious about it as the following:
It is flammable, harmful if swallowed and it is irritating to respiratory system and skin. Besides, it has limited evidence of a carcinogenic effect and the risk of serious damage to eyes. What's more, it may cause sensitisation by skin contact. In case of contact with eyes, you should rinse immediately with plenty of water and seek medical advice. When using it, you need wear suitable protective clothing, gloves and eye/face protection.

You can still convert the following datas into molecular structure:
(1)Canonical SMILES: C=CC(=O)OCC(C(F)F)(F)F
(2)InChI: InChI=1S/C6H6F4O2/c1-2-4(11)12-3-6(9,10)5(7)8/h2,5H,1,3H2
(3)InChIKey: VHJHZYSXJKREEE-UHFFFAOYSA-N

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