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Cas Database |
| Name |
3,5-DIMETHOXYTOLUENE |
EINECS | 224-048-9 |
| CAS No. | 4179-19-5 | Density | 0.99 g/cm3 |
| PSA | 18.46000 | LogP | 2.01220 |
| Solubility | N/A | Melting Point |
61-62 °C |
| Formula | C9H12O2 | Boiling Point | 244 °C at 760 mmHg |
| Molecular Weight | 152.193 | Flash Point | 87.5 °C |
| Transport Information | N/A | Appearance | Clear colorless to yellow liquid |
| Safety | 26-36 | Risk Codes | 36/37/38 |
| Molecular Structure |
|
Hazard Symbols |
 Xi
|
| Synonyms |
Toluene,3,5-dimethoxy- (6CI,7CI,8CI);1,3-Dimethoxy-5-methylbenzene;1-Methyl-3,5-dimethoxybenzene;5-Methyl-1,3-dimethoxybenzene;NSC 72352; |
Article Data | 75 |
3,5-DIMETHOXYTOLUENE Synthetic route
| Conditions | Yield |
|---|---|
| With potassium carbonate In acetone for 6h; Heating; | 100% |
| With potassium carbonate In acetone Reflux; Inert atmosphere; | 89% |
| With potassium carbonate In acetone for 6h; Heating; | 76% |
- 73569-69-4
1-methylmethoxy-3,5-dimethoxybenzene
- 4179-19-5
1,3-dimethoxy-5-methylbenzene
| Conditions | Yield |
|---|---|
| With hydrogen; palladium on activated charcoal In methanol under 1706.6 Torr; for 0.5h; | 98% |
| Conditions | Yield |
|---|---|
| With hydrogenchloride; hydrogen; palladium on activated charcoal In methanol at 20℃; under 760.051 Torr; for 2h; | 96% |
| With hydrogen; palladium on activated charcoal In ethanol at 20℃; | 87% |
| With hydrogenchloride; hydrogen; palladium on activated charcoal In ethanol | |
| (i) MeMgI, (ii) H2, H2SO4, Pd-C; Multistep reaction; |
| Conditions | Yield |
|---|---|
| With potassium carbonate In acetone Reflux; | 95% |
| With potassium carbonate In acetone for 24h; Heating; | 92% |
| With potassium carbonate In acetone for 24h; Heating; | 92% |
| Conditions | Yield |
|---|---|
| With potassium carbonate; dimethyl sulfate In acetone for 24h; Reflux; | 94% |
| With potassium carbonate; dimethyl sulfate In acetonitrile | 82% |
- 64286-79-9
3,5-dimethoxy-1-methylcyclohexa-2,5-diene-1-carboxylic acid
- 4179-19-5
1,3-dimethoxy-5-methylbenzene
| Conditions | Yield |
|---|---|
| With lead(IV) tetraacetate In benzene | 91% |
- 157843-81-7
3,5-Dimethoxybenzyl pivalate
- 4179-19-5
1,3-dimethoxy-5-methylbenzene
| Conditions | Yield |
|---|---|
| With bis(1,5-cyclooctadiene)nickel (0); sodium formate; 1,2-bis-(dicyclohexylphosphino)ethane In toluene at 140℃; for 24h; Inert atmosphere; Schlenk technique; | 91% |
| Conditions | Yield |
|---|---|
| With lithium aluminium tetrahydride In diethyl ether | 90.3% |
| With water; zinc In acetonitrile at 25℃; for 4h; Sealed tube; Inert atmosphere; | 66% |
| With water; zinc In acetonitrile at 25℃; for 4h; Inert atmosphere; Sealed tube; | 66% |
- 60319-09-7
3,5-dimethoxyphenyl trifluoromethanesulfonate
- 917-54-4
methyllithium
- 4179-19-5
1,3-dimethoxy-5-methylbenzene
| Conditions | Yield |
|---|---|
| With tris-(dibenzylideneacetone)dipalladium(0); DavePhos In toluene at 50℃; Inert atmosphere; Schlenk technique; | 88% |
| Conditions | Yield |
|---|---|
| With potassium In tetrahydrofuran for 24h; Ambient temperature; | 87% |
| With potassium In tetrahydrofuran for 24h; Ambient temperature; | 87% |
3,5-DIMETHOXYTOLUENE Chemical Properties
IUPAC Name: 3,5-Dimethoxytoluene
The MF of 3,5-Dimethoxytoluene (4179-19-5) is C9H12O2.
The MW of 3,5-Dimethoxytoluene (4179-19-5) is 152.19.
Synonyms of 3,5-Dimethoxytoluene (4179-19-5): Benzene, 1,3-dimethoxy-5-methyl- ; Toluene, 3,5-dimethoxy- ; 1,3-Dimethoxy-5-methylbenzene ; 3,5-dimethoxytoluene
Product Categories: Aromatic Ethers;Ethers;Organic Building Blocks;Oxygen Compounds
Form: Clear colorless to yellow liquid
Index of Refraction: 1.489
EINECS: 224-048-9
Density: 0.99 g/ml
Flash Point: 87.5 °C
Boiling Point: 244 °C
Melting Point: 61-62 °C
BRN: 2043558
3,5-DIMETHOXYTOLUENE Safety Profile
Safety information of 3,5-Dimethoxytoluene (4179-19-5):
Hazard Codes 
Xi
Risk Statements
36/37/38 Irritating to eyes, respiratory system and skin
Safety Statements
26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
36 Wear suitable protective clothing
WGK Germany 3
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