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3-Methoxy-1-propene

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Name

3-Methoxy-1-propene

EINECS 210-997-6
CAS No. 627-40-7 Density 0.751 g/cm3
PSA 9.23000 LogP 0.81880
Solubility Insoluble in water Melting Point -115.8°C (estimate)
Formula C4H8O Boiling Point 46 °C at 760 mmHg
Molecular Weight 72.1069 Flash Point - 23 °C
Transport Information N/A Appearance N/A
Safety 3/7-9-16-36/37/39-26 Risk Codes 11-19-36-22-12
Molecular Structure Molecular Structure of 627-40-7 (ALLYL METHYL ETHER) Hazard Symbols HighlyF+HarmfulXnFlammableF
Synonyms

Methyl 2-propenyl ether;

Article Data 78

3-Methoxy-1-propene Synthetic route

107-98-2

1-methoxy-2-propanol

627-40-7

methylallylether

Conditions
ConditionsYield
With zirconium(IV) oxide at 100℃; for 3h; Temperature; Reagent/catalyst;96.6%
107-18-6

allyl alcohol

74-88-4

methyl iodide

627-40-7

methylallylether

Conditions
ConditionsYield
With dimsylsodium In dimethyl sulfoxide Ambient temperature;93%
With silver(l) oxide
With sodium hydride In paraffin
6044-68-4

3,3-dimethoxyprop-1-ene

627-40-7

methylallylether

Conditions
ConditionsYield
With benzo[1,3,2]dioxaborole In benzene Ambient temperature;88%
124-41-4

sodium methylate

106-95-6

allyl bromide

627-40-7

methylallylether

Conditions
ConditionsYield
In methanol80%
106-95-6

allyl bromide

627-40-7

methylallylether

Conditions
ConditionsYield
for 48h; Heating;78%
67-56-1

methanol

107-05-1

3-chloroprop-1-ene

627-40-7

methylallylether

Conditions
ConditionsYield
With sodium methylate at 35 - 45℃; for 4h;74.1%
Stage #1: methanol With sodium Inert atmosphere; Reflux;
Stage #2: 3-chloroprop-1-ene for 4h; Inert atmosphere; Reflux;
67%
627-41-8

propargyl alcohol methyl ether

A

557-17-5

methyl propyl ether

B

627-40-7

methylallylether

Conditions
ConditionsYield
With hydrogen; palladium dichloride In N,N-dimethyl-formamide under 18751.5 Torr; for 0.666667h; Product distribution; Ambient temperature; various time;A 2%
B 68.4%
Stage #1: propargyl alcohol methyl ether With pyridine In toluene for 0.166667h; Glovebox;
Stage #2: With hydrogen In toluene at 120℃; under 37503.8 Torr; for 12h; Glovebox;
107-18-6

allyl alcohol

77-78-1

dimethyl sulfate

627-40-7

methylallylether

Conditions
ConditionsYield
With sodium hydroxide; N-benzyl-N,N,N-triethylammonium chloride In water at 40 - 45℃; for 3h;65%
With sodium hydride 1. 1 h; 2.overnight; Multistep reaction;
With sodium hydride In xylene Heating;
With sodium hydride In xylene
4885-02-3

Dichloromethyl methyl ether

78338-53-1, 85263-66-7

(Z)-(3-methoxyprop-1-ene-1,2-diyl)bis(trimethylstannane)

627-40-7

methylallylether

Conditions
ConditionsYield
With aluminium trichloride61%
25439-17-2

allyl alcohol; aluminium allylate

74-88-4

methyl iodide

627-40-7

methylallylether

Conditions
ConditionsYield
In N,N-dimethyl-formamide at 59 - 70℃; for 48h;60%

3-Methoxy-1-propene Specification

The 3-Methoxy-1-propene, with the CAS registry number of 627-40-7, is also known as Methyl 2-propenyl ether. Its EINECS registry number is 210-997-6. This chemical's molecular formula is C4H8O and molecular weight is 72.11. What's more, its IUPAC name is 3-Methoxyprop-1-ene. In addition, it must be stored in airtight containers and placed in a dry, cool place. Meanwhile, it should avoid contact with oxidant.

Physical properties about the 3-Methoxy-1-propene are: (1)ACD/LogP: 0.75; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): 0.75; (4)ACD/LogD (pH 7.4): 0.75; (5)#H bond acceptors: 1; (6)#H bond donors: 0; (7)#Freely Rotating Bonds: 2; (8)Index of Refraction: 1.376; (9)Molar Refractivity: 22.05 cm3; (10)Molar Volume: 96 cm3; (11)Surface Tension: 18.8 dyne/cm; (12)Density: 0.751 g/cm3; (13)Enthalpy of Vaporization: 27.79 kJ/mol; (14)Boiling Point: 46 °C at 760 mmHg; (15)Vapour Pressure: 354 mmHg at 25 °C.

Preparation: this chemical is prepared by reaction of Prop-2-en-1-ol with Iodomethane at ambient temperature. The reaction needs solvent Dimethylsulfoxide. The yield is about 93 %.


Uses: it is used to produce other chemicals. For example, it is used to produce 1,2-Dibromo-3-methoxy-propane. This reaction needs reagent Br2. Meanwhile, it needs solvent CHCl3. The reaction temperature is 0 - 20 °C. The yield is about 73 %.

When you are using this chemical, please be cautious about it as the following:
As a chemical, it is irritating to eyes and harmful if swallowed. During using it, wear suitable protective clothing, gloves and eye/face protection. If contact with eyes accidently, rinse immediately with plenty of water and seek medical advice. Besides, this chemical is highly flammable, and it may catch fire in contact with an ignition source.

You can still convert the following datas into molecular structure:
(1) SMILES:C=CCOC
(2) InChI:InChI=1/C4H8O/c1-3-4-5-2/h3H,1,4H2,2H3
(3) InChIKey:FASUFOTUSHAIHG-UHFFFAOYAU

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