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Name |
4-Chloro-1,8-naphthalic anhydride |
EINECS | 223-760-7 |
CAS No. | 4053-08-1 | Density | 1.565 g/cm3 |
PSA | 43.37000 | LogP | 2.80380 |
Solubility | Hydrolyzes in water. | Melting Point |
202-206 °C (dec.) |
Formula | C12H5ClO3 | Boiling Point | 450.9 °C at 760 mmHg |
Molecular Weight | 232.623 | Flash Point | 208.3 °C |
Transport Information | N/A | Appearance | beige to brown powder |
Safety | 24/25 | Risk Codes | 36/37/38 |
Molecular Structure | Hazard Symbols | Xi | |
Synonyms |
Naphthalicanhydride, 4-chloro- (7CI,8CI);4-Chloro-1,8-naphthalenedicarboxylic anhydride;4-Chloronaphthalic anhydride; |
Article Data | 12 |
Conditions | Yield |
---|---|
With copper(II) acetate dihydrate; manganese(II) acetate dihydrate; oxygen; acetic acid; potassium bromide at 100℃; | 93% |
Multi-step reaction with 4 steps 1: Pb3O4 2: aq. NaOH / methanol 3: HCl / diethyl ether 4: Na2Cr2O7, AcOH View Scheme |
Conditions | Yield |
---|---|
With sodium hydroxide; phosphoric acid; chlorine for 3h; Ambient temperature; | 82% |
With hydrogenchloride; potassium permanganate; phosphoric acid; sodium hydroxide In water at 20℃; for 3h; | 40% |
5-chloroacenaphthene
A
p-chloro-1,8-naphthalicanhydride
B
5-chloro-acenaphthene-1,2-dione
Conditions | Yield |
---|---|
With sodium dichromate; acetic acid at 120℃; |
4-chloro-naphthalene-1,8-dicarboxylic acid
p-chloro-1,8-naphthalicanhydride
Conditions | Yield |
---|---|
at 120 - 125℃; | |
With acetic acid | |
With acetic acid | |
at 120 - 125℃; |
Conditions | Yield |
---|---|
With chloroform; chlorine Behandeln des entstandenen 5-Chlor-acenaphthen mit Natriumdichromat und Eisessig; |
2,5-Dichloracenaphthen
p-chloro-1,8-naphthalicanhydride
Conditions | Yield |
---|---|
With sodium dichromate; acetic acid |
4-hydroxy-1,8-naphthalic anhydride
phosphorus pentachloride
p-chloro-1,8-naphthalicanhydride
Conditions | Yield |
---|---|
at 190 - 200℃; |
5-Chloracenaphthen-2-ol
p-chloro-1,8-naphthalicanhydride
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: HCl / diethyl ether 2: Na2Cr2O7, AcOH View Scheme |
5-Chloracenaphthen-2-ol-acetat
p-chloro-1,8-naphthalicanhydride
Conditions | Yield |
---|---|
Multi-step reaction with 3 steps 1: aq. NaOH / methanol 2: HCl / diethyl ether 3: Na2Cr2O7, AcOH View Scheme |
Conditions | Yield |
---|---|
In 1-methyl-pyrrolidin-2-one at 150℃; for 4h; | 98.9% |
Molecular Structure of 1H,3H-Naphtho(1,8-cd)pyran-1,3-dione, 6-chloro- (CAS NO.4053-08-1):
Molecular Formula: C12H5ClO3
Molecular Weight: 232.62
CAS Registry Number: 4053-08-1
H bond acceptors: 3
H bond donors: 0
Freely Rotating Bonds: 0
Polar Surface Area: 43.37 Å2
Index of Refraction: 1.715
Molar Refractivity: 58.41 cm3
Molar Volume: 148.6 cm3
Surface Tension: 66.9 dyne/cm
Density: 1.565 g/cm3
Flash Point: 208.3 °C
Enthalpy of Vaporization: 70.99 kJ/mol
Boiling Point: 450.9 °C at 760 mmHg
Vapour Pressure: 2.53E-08 mmHg at 25°C
EINECS: 223-760-7
Melting Point: 207-210 °C
Storage temp: 2-8 °C
Sensitive: Moisture Sensitive
BRN: 178072
Product Categories: Intermediates of Dyes and Pigments
InChI
InChI=1/C12H5ClO3/c13-9-5-4-8-10-6(9)2-1-3-7(10)11(14)16-12(8)15/h1-5H
Smiles
O=C1OC(=O)c2cccc3c2c1ccc3Cl
1. | orl-rat LD50:3460 mg/kg | NTIS** National Technical Information Service. (Springfield, VA 22161) (Formerly U.S. Clearinghouse for Scientific and Technical Information) OTS0535458 . |
Reported in EPA TSCA Inventory.
Moderately toxic by ingestion. When heated to decomposition it emits toxic vapors of Cl−.
Safety information of 1H,3H-Naphtho(1,8-cd)pyran-1,3-dione, 6-chloro- (CAS NO.4053-08-1):
Hazard Codes: Xi
Risk Statements:
36/37/38: Irritating to eyes, respiratory system and skin
Safety Statements:
24/25: Avoid contact with skin and eyes
WGK Germany: 2
RTECS: QL6127295
1H,3H-Naphtho(1,8-cd)pyran-1,3-dione, 6-chloro- , with CAS number of 4053-08-1, can be called 1H,3H-Naphtho[1,8-cd]pyran-1,3-dione, 6-chloro- ; 6-Chloro-1H,3H-benzo[de]isochromene-1,3-dione ; 4-Chloro-1,8-naphthalic anhydride ; 6-Chloro-1H,3H-naphtho(1,8-cd)pyran-1,3-dione . It is a beige to brown powder, 1H,3H-Naphtho(1,8-cd)pyran-1,3-dione, 6-chloro- (CAS NO.4053-08-1) is used as synthetic dyes, pigments, fluorescent brighteners and other important raw materials.