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Name	5-Chloro-1,3-xylene	EINECS	N/A
CAS No.	556-97-8	Density	1,04 g/cm3
PSA	0.00000	LogP	2.95680
Solubility	N/A	Melting Point	-41.95°C (estimate)
Formula	C8H9 Cl	Boiling Point	188.1 ºC at 760 mmHg
Molecular Weight	140.612	Flash Point	63.1 ºC
Transport Information	N/A	Appearance	liquid
Safety	Experimental reproductive effects. When heated to decomposition it emits toxic fumes of Cl⁻.	Risk Codes	36/37/38
Molecular Structure		Hazard Symbols	Xi
Synonyms	m-Xylene,5-chloro- (8CI); 1-Chloro-3,5-dimethylbenzene; 3,5-Dimethylchlorobenzene;3,5-Dimethylphenyl chloride; 3-Methyl-5-chlorotoluene;5-Chloro-1,3-dimethylbenzene; 5-Chloro-m-xylene; 5-Chloro-m-xylene	Article Data	10

5-Chloro-1,3-xylene Synthetic route

: <(3,5-Dimethylphenyl)azo>pyrrolidine

: 556-97-8
1-chloro-3,5-dimethylbenzene

Conditions

Conditions	Yield
With hydrogenchloride; copper(l) chloride	54%
With hydrogenchloride; copper(l) chloride Product distribution; triazene moiety as protecting group for aromatic amines; var. triazenes;

: 108-69-0
3,5-dimethylaminoaniline

: 556-97-8
1-chloro-3,5-dimethylbenzene

Conditions

Conditions	Yield
With hydrogenchloride Diazotization.Behandlung der Diazoniumsalz-Loesung mit CuCl;

dibromide of 5-chloro-1.3-dimethyl-cyclohexadiene: dibromide of 5-chloro-1.3-dimethyl-cyclohexadiene

: 556-97-8
1-chloro-3,5-dimethylbenzene

Conditions

Conditions	Yield
With quinoline

: 95-47-6
o-xylene

A: 95-66-9
2,4-dimethylchlorobenzene

B: 556-97-8
1-chloro-3,5-dimethylbenzene

C: 95-72-7
2-chloro-1,4-dimethyl-benzene

D: 6781-98-2
2,6-dimethyl-1-chlorobenzene

E: 615-60-1
4-chloro-1,2-dimethylbenzene

F: 608-23-1
3-chloro-o-xylene

G: 20824-80-0
1,2-dichloro-4,5-dimethyl-benzene

H: 68266-67-1
1,2-dichloro-3,4-dimethyl-benzene

I: 34060-72-5
2-methyl-5-chlorobenzyl chloride

J: 52331-02-9
1,4-dichloro-2,3-dimethyl-benzene

K: 70172-92-8
3,5-dichloro-o-xylene

L: 552-45-4
1-chloromethyl-2-methylbenzene

M: 55676-90-9
alpha,2-dichloro-6-methyltoluene

Conditions

Conditions	Yield
With chlorine; the fluorine-containing K-L-type zeolite In 1,2-dichloro-ethane at 80℃; for 1.75 - 3.66667h; Product distribution / selectivity;
With chlorine; a K-L-type zeolite In 1,4-dioxane; 1,2-dichloro-ethane at 80℃; for 6.75h;

...Expand

: 7758-89-6
copper(I) chloride

: 108-69-0
3,5-dimethylaminoaniline

: 556-97-8
1-chloro-3,5-dimethylbenzene

Conditions

Conditions	Yield
With hydrogenchloride; sodium nitrite In water

: 556-97-8
1-chloro-3,5-dimethylbenzene

A: 17057-88-4
3,5-dimethylbiphenyl

B: 98-80-6
phenylboronic acid

Conditions

Conditions	Yield
With cesium fluoride; Pd(dba)2 In toluene	A n/a B 99%

: 556-97-8
1-chloro-3,5-dimethylbenzene

: 108-69-0
3,5-dimethylaminoaniline

Conditions

Conditions	Yield
With ammonium hydroxide; potassium phosphate In dimethyl sulfoxide at 80℃; UV-irradiation;	99%
Multi-step reaction with 2 steps 1.1: sulfuric acid; nitric acid / 30 °C / Cooling with ice 2.1: palladium on activated charcoal / ethanol / 0.5 h / 50 °C / Autoclave 2.2: 0.83 h / 65 °C / 2250.23 Torr / Autoclave View Scheme

: 556-97-8
1-chloro-3,5-dimethylbenzene

: 100-46-9
benzylamine

: 124043-95-4
N-benzyl-3,5-dimethylaniline

Conditions

Conditions	Yield
With potassium phosphate In dimethyl sulfoxide at 80℃; UV-irradiation;	99%

: 556-97-8
1-chloro-3,5-dimethylbenzene

: 98-80-6
phenylboronic acid

: 17057-88-4
3,5-dimethylbiphenyl

Conditions

Conditions	Yield
With cesium fluoride; Pd(dba)2 In toluene	98%
With potassium phosphate; C75H58Cl2N4Pd In water; isopropyl alcohol at 25℃; for 4.5h; Reagent/catalyst; Suzuki-Miyaura Coupling; Schlenk technique;	98%
With potassium phosphate; C20H28Br2N2Pd In water; isopropyl alcohol at 25℃; for 7.5h; Reagent/catalyst; Suzuki-Miyaura Coupling;	95%

: 556-97-8
1-chloro-3,5-dimethylbenzene

: 2835-99-6
4-amino-3-methylphenol

: 1198117-98-4
4-(3,5-dimethylphenylamino)-3-methyl-phenol

Conditions

Conditions	Yield
With chloro[2-(dicyclohexylphosphino)-3,6-dimethoxy-2',4',6'-triisopropyl-1,1'-biphenyl][2-(2-aminoethyl)phenyl]palladium(ll); sodium t-butanolate In 1,4-dioxane at 110℃; for 3h; Inert atmosphere;	97%

5-Chloro-1,3-xylene Chemical Properties

Chemical Name: 5-Chloro-1,3-xylene
IUPAC NAME: 1-Chloro-3,5-dimethylbenzene
CAS No.: 556-97-8
Molecular Formula: C₈H₉Cl
Molecular Weight: 140.61 g/mol
Density: 1.049 g/cm³
Flash Point: 63.1 °C
Boiling Point: 188.1 °C at 760 mmHg
Following is the structure of 1-Chloro-3,5-xylene (CAS No.556-97-8):

Product Categories about 1-Chloro-3,5-xylene (CAS No.556-97-8) are Halogen toluene ; Chlorine Compounds
The chemical synonymous of 1-Chloro-3,5-xylene (CAS No.556-97-8) are 5-Chloro-M-Xylene ; 1-Chloro-3,5-Dimethylbenzene ; 1-Chloro-3,5-Xylene ; 3,5-Dimethylchlorobenzene ; 3,5-Dimethylphenylchloride ; 5-Chloro-1,3-Xylene ; 5-Chloro-M-Xylen ; 1,3-Dimethyl-5-Chlorobenzene

5-Chloro-1,3-xylene Safety Profile

Experimental reproductive effects. When heated to decomposition it emits toxic fumes of Cl⁻.
Hazard Codes: Irritant Xi
Risk Statements about 1-Chloro-3,5-xylene (CAS No.556-97-8):
R36/37/38:Irritating to eyes, respiratory system and skin.
Safety Statements about 1-Chloro-3,5-xylene (CAS No.556-97-8):
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36:Wear suitable protective clothing.
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection.

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