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Aluminum, (N,N-dimethylmethanamine)trihydro-, (T-4)- |
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The Molecular Structure of Aluminum, (N,N-dimethylmethanamine)trihydro-, (T-4)- (CAS NO.17013-07-9):
Molecular Formula: C3H12AlN
Molecular Weight: 89.115618 g/mol
IUPAC: aluminum; N,N-dimethylmethanamine; hydride
ACD/LogP: 0.06
ACD/LogD (pH 5.5): -3.01
ACD/LogD (pH 7.4): -2.22
ACD/BCF (pH 5.5): 1
ACD/BCF (pH 7.4): 1
ACD/KOC (pH 5.5): 1
ACD/KOC (pH 7.4): 1
Polar Surface Area: 3.24Å2
Enthalpy of Vaporization: 22.94 kJ/mol
Boiling Point: 2.8 °C at 760 mmHg
Vapour Pressure: 1720 mmHg at 25°C
AlH3 readily forms adducts with strong Lewis bases e.g. 1:1 and 1:2 complexes with trimethylamine .The 1:1 complex with trimethylamine is tetrahedral in the gas phase, but in the solid phase it is dimeric with bridging hydrogens , (NMe3Al(μ-H))2.The 1:2 complex has a trigonal bipyramidal structure. Some adducts (e.g. dimethylethylamine alane, NMe2Et.AlH3) thermally decompose to give aluminium metal and may have use in MOCVD(metalorganic chemical vapour deposition) applications.
An unstable, dangerous compound. Explodes on contact with water. Ignites in moist air. When heated to decomposition it emits toxic fumes of NOx. See also AMINES, HYDRIDES, and ALUMINUM COMPOUNDS.
Aluminum, (N,N-dimethylmethanamine)trihydro-, (T-4)- (CAS NO.17013-07-9) is also called as EINECS 240-866-9 ; Trihydro(trimethylamine)aluminium .