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Bensulide

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Name

Bensulide

EINECS N/A
CAS No. 741-58-2 Density 1.261g/cm3
PSA 140.21000 LogP 5.89490
Solubility 25mg/L(room temperature) Melting Point 34.4°C
Formula C14H24 N O4 P S3 Boiling Point 487.2oC at 760 mmHg
Molecular Weight 397.521 Flash Point 248.4oC
Transport Information N/A Appearance N/A
Safety Poison by ingestion. Moderately toxic by skin contact. An herbicide. When heated to decomposition it emits very toxic fumes of NOx, SOx, and POx. See also ESTERS. Risk Codes 22-50/53
Molecular Structure Molecular Structure of 741-58-2 (BENSULIDE) Hazard Symbols Highly toxic, cholinesterase inhibitor. Use may be restricted.
Synonyms

Phosphorodithioicacid, O,O-diisopropyl ester, S-ester with N-(2-mercaptoethyl)benzenesulfonamide(7CI,8CI); Bensulide; Betasan; Disan; Disan (pesticide);N-[2-(O,O-Diisopropyldithiophosphoryl)ethyl]benzenesulfonamide; O,O-Diisopropyl2-(benzenesulfonamido)ethyl dithiophosphate; O,O-DiisopropylS-(2-benzenesulfonylaminoethyl) phosphorodithioate; Prefar; R 4461; S-b-(Benzenesulfonamido)ethylO,O-diisopropyl dithiophosphate; SAP; SAP (herbicide)

Article Data 6

Bensulide Chemical Properties

Chemistry informtion about Bensulide (CAS NO.741-58-2) is:
IUPAC Name: N-[2-Di(Propan-2-Yloxy)Phosphinothioylsulfanylethyl]Benzenesulfonamide
Synonyms: Bensulide ; Bensulide(Content>35%) ; Bensumac ; Bensumec ; Bensumec(R) ; Betasan ; Betasan(R) ; Exporsan
Product Categories: A-BAlphabetic ; Alpha sort ; B ; BA - BHPesticides&Metabolites ; Herbicides ; Organophosphorous ; Pesticides&Metabolites 
MF: C14H24NO4PS3
MW: 397.51
EINECS: 212-010-4
Density: 1.261 g/cm3
Flash Point: 248.4 °C
Boiling Point: 487.2 °C at 760 mmHg
Vapour Pressure: 1.21E-09 mmHg at 25°C
Enthalpy of Vaporization: 75.3 kJ/mol
Storage temp.: 2-8°C
Following is the molecular structure of Bensulide (CAS NO.741-58-2) is:

Bensulide Uses

Bensulide (CAS NO.741-58-2) can be used as an insecticide.Also it used on vegetable crops such as carrots, cucumbers, peppers, and melons and in cotton and turfgrass to control annual grasses (such as bluegrass and crabgrass) and broadleaf weeds. It is often formulated as an emulsifiable liquid and applied before the weed seeds germinate in order to prevent them from germinating.

Bensulide Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
mouse LD50 intraperitoneal 630mg/kg (630mg/kg)   Japan Pesticide Information. Vol. (27), Pg. 11, 1976.
mouse LD50 oral 1540mg/kg (1540mg/kg)   Japan Pesticide Information. Vol. (27), Pg. 11, 1976.
mouse LD50 subcutaneous 630mg/kg (630mg/kg)   Japan Pesticide Information. Vol. (27), Pg. 11, 1976.
quail LD50 oral 1386mg/kg (1386mg/kg)   Pesticide Manual. Vol. 9, Pg. 63, 1991.
rabbit LD50 skin 2gm/kg (2000mg/kg)   World Review of Pest Control. Vol. 9, Pg. 119, 1970.
rat LD50 oral 271mg/kg (271mg/kg)   Farm Chemicals Handbook. Vol. -, Pg. C42, 1991.
rat LD50 skin 3950mg/kg (3950mg/kg)   Pesticide Manual. Vol. 9, Pg. 63, 1991.
rat LD50 unreported 770mg/kg (770mg/kg)   "Chemistry of Pesticides," Melnikov, N.N., New York, Springer-Verlag New York, Inc., 1971Vol. -, Pg. 375, 1971.

Bensulide Safety Profile

Poison by ingestion. Moderately toxic by skin contact. An herbicide. When heated to decomposition it emits very toxic fumes of NOx, SOx, and POx. See also ESTERS.
Hazard Codes:
HarmfulXn
DangerousN
Risk Statements:
R22:Harmful if swallowed. 
R50/53:Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Safety Statements:
S24:Avoid contact with skin. 
S36:Wear suitable protective clothing. 
S60:This material and its container must be disposed of as hazardous waste. 
S61:Avoid release to the environment. Refer to special instructions / safety data sheets.
RIDADR: UN 2811 6.1/PG 3
RTECS: TE0250000

Bensulide Specification

Bensulide (CAS NO.741-58-2) is an organophosphate acetylcholinesterase inhibitor. It can be absorbed on root surfaces and a small amount is absorbed by the roots. Little or none is translocated upward to the leaves. It is toxic to aquatic organisms, bees, and slightly toxic to birds.

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