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Benzenesulfonamide,N-methyl-

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Name

Benzenesulfonamide,N-methyl-

EINECS 225-965-7
CAS No. 5183-78-8 Density 1.222 g/cm3
PSA 54.55000 LogP 2.06640
Solubility It is soluble in water. Melting Point 31 °C
Formula C7H9NO2S Boiling Point 284 °C at 760 mmHg
Molecular Weight 171.22 Flash Point 125.6 °C
Transport Information N/A Appearance N/A
Safety 22-24/25 Risk Codes N/A
Molecular Structure Molecular Structure of 5183-78-8 (N-METHYLBENZENESULFONAMIDE) Hazard Symbols N/A
Synonyms

DellatolMMA;N-Methylbenzenesulfonamide;N-Methylphenylsulfonamide;NSC 15404;N-(Phenylsulfonyl)methanamine;methyl(phenylsulfonyl)amine;

Article Data 56

Benzenesulfonamide,N-methyl- Specification

The Benzenesulfonamide,N-methyl-, with the CAS registry number 5183-78-8 and EINECS registry number 225-965-7, has the systematic name of N-methylbenzenesulfonamide. And the molecular formula of the chemical is C7H9NO2S. What's more, while dealing with this chemical, you should not breathe dust and then try to avoid contacting with skin and eyes.

The characteristics of Benzenesulfonamide,N-methyl- are as followings: (1)ACD/LogP: 0.97; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): 0.97; (4)ACD/LogD (pH 7.4): 0.97; (5)ACD/BCF (pH 5.5): 3.23; (6)ACD/BCF (pH 7.4): 3.23; (7)ACD/KOC (pH 5.5): 80.53; (8)ACD/KOC (pH 7.4): 80.52; (9)#H bond acceptors: 3; (10)#H bond donors: 1; (11)#Freely Rotating Bonds: 1; (12)Polar Surface Area: 45.76 Å2; (13)Index of Refraction: 1.538; (14)Molar Refractivity: 43.84 cm3; (15)Molar Volume: 140 cm3; (16)Polarizability: 17.38×10-24cm3; (17)Surface Tension: 39.7 dyne/cm; (18)Density: 1.222 g/cm3; (19)Flash Point: 125.6 °C; (20)Enthalpy of Vaporization: 52.3 kJ/mol; (21)Boiling Point: 284 °C at 760 mmHg; (22)Vapour Pressure: 0.00305 mmHg at 25°C.

Preparation of Benzenesulfonamide,N-methyl-: This chemical can be prepared by benzenesulfonyl chloride and methylamine. The reaction will need reagent H2O. The reaction time is 15 minutes with heating, and the yield is about 93%. 

Uses of Benzenesulfonamide,N-methyl-: It can react with benzotriazol-1-yl-methanol to produce N-benzotriazol-1-ylmethyl-N-methyl-benzenesulfonamide. This reaction will need reagent p-toluenesulfonic acid, and the menstruum toluene. The reaction time is 16 hours with heating, and the yield is about 94%.   

Addtionally, the following datas could be converted into the molecular structure:
(1)SMILES: O=S(=O)(NC)c1ccccc1
(2)InChI: InChI=1/C7H9NO2S/c1-8-11(9,10)7-5-3-2-4-6-7/h2-6,8H,1H3
(3)InChIKey: SVDVKEBISAOWJT-UHFFFAOYAD

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