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Bis(dimethylamino)dimethylsilane

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Name

Bis(dimethylamino)dimethylsilane

EINECS 223-200-1
CAS No. 3768-58-9 Density 0.822 g/cm3
PSA 6.48000 LogP 0.81140
Solubility Hydrolyzes in water. Melting Point -98 °C(lit.)
Formula C6H18N2Si Boiling Point 128.5 °C at 760 mmHg
Molecular Weight 146.308 Flash Point 22.3 °C
Transport Information UN 2924 3/PG 2 Appearance clear colourless liquid
Safety 16-26-36/37/39-45-27 Risk Codes 11-15-34
Molecular Structure Molecular Structure of 3768-58-9 (Bis(dimethylamino)dimethylsilane) Hazard Symbols HighlyF+; CorrosiveC
Synonyms

Silanediamine,hexamethyl- (6CI,7CI,8CI,9CI);BDMADS;Bis(N,N-dimethylamino)dimethylsilane;Dimethylbis(dimethylamino)silane;Dimethylsilylbis(dimethylamine);Hexamethylsilanediamine;LS 1440;N,N,N',N',1,1-hexamethylsilanediamine;Silanediamine, hexamethyl-;silanediamine, N,N,N',N',1,1-hexamethyl-;

Article Data 15

Bis(dimethylamino)dimethylsilane Specification

The Silanediamine,N,N,N',N',1,1-hexamethyl-, with the CAS registry number 3768-58-9 and EINECS registry number 223-200-1, has the systematic name of N,N,N',N',1,1-hexamethylsilanediamine. It is a kind of clear colourless liquid which is moisture sensitive. And the molecular formula of the chemical is C6H18N2Si.

The characteristics of Silanediamine,N,N,N',N',1,1-hexamethyl- are as followings: (1)ACD/LogP: 0.74; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): -2.4; (4)ACD/LogD (pH 7.4): -2.18; (5)ACD/BCF (pH 5.5): 1; (6)ACD/BCF (pH 7.4): 1; (7)ACD/KOC (pH 5.5): 1; (8)ACD/KOC (pH 7.4): 1; (9)#H bond acceptors: 2; (10)#H bond donors: 0; (11)#Freely Rotating Bonds: 2; (12)Polar Surface Area: 6.48 Å2; (13)Index of Refraction: 1.43; (14)Molar Refractivity: 46 cm3; (15)Molar Volume: 177.8 cm3; (16)Polarizability: 18.23×10-24cm3; (17)Surface Tension: 21.1 dyne/cm; (18)Density: 0.822 g/cm3; (19)Flash Point: 22.3 °C; (20)Enthalpy of Vaporization: 36.62 kJ/mol; (21)Boiling Point: 128.5 °C at 760 mmHg; (22)Vapour Pressure: 10.6 mmHg at 25°C.

Uses of Silanediamine,N,N,N',N',1,1-hexamethyl-: It can react with butane-1,4-diol to produce 2,2-dimethyl-[1,3,2]dioxasilepane. And the yield is about 40%.   

You should be cautious while dealing with this chemical. It is a kind of highly flammable chemical which may cause burns, and it will liberate extremely flammable gases if contact with water. Therefore, you had better take the following instructions: Keep away from sources of ignition - No smoking; Wear suitable protective clothing, gloves and eye/face protection, and if in case of contacting with eyes, rinse immediately with plenty of water and seek medical advice; In case of accident or if you feel unwell, seek medical advice immediately (show label where possible); Take off immediately all contaminated clothing.

Addtionally, the following datas could be converted into the molecular structure:
(1)SMILES: N(C)(C)[Si](N(C)C)(C)C
(2)InChI: InChI=1/C6H18N2Si/c1-7(2)9(5,6)8(3)4/h1-6H3
(3)InChIKey: QULMGWCCKILBTO-UHFFFAOYAN

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