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Name	CADMIUM CHLORIDE	EINECS	233-296-7
CAS No.	10108-64-2	Density	4.047 g/cm³
PSA	0.00000	LogP	1.37650
Solubility	1400 g/L (20 °C) in water	Melting Point	568 °C
Formula	CdCl₂	Boiling Point	967 °C
Molecular Weight	183.316	Flash Point	960°C
Transport Information	UN 3082 9/PG 3	Appearance	white crystalline solid
Safety	53-45-61-60-36/37-28	Risk Codes	45-46-60-61-25-26-48/23/25-51/53-50/53-48/20/22-23-22
Molecular Structure		Hazard Symbols	T, N, T+
Synonyms	Cadmiumchloride;Cadmium dichloride;Dichlorocadmium;NSC 51148;Cadmium chloride(CdCl2);	Article Data	205

CADMIUM CHLORIDE Synthetic route

: 7791-25-5
sulfuryl dichloride

: cadmium(II) sulphide

: 10108-64-2
cadmium(II) chloride

Conditions

Conditions	Yield
In neat (no solvent) 250°C (4 h/CO2 stream);;	96%
In neat (no solvent) 250°C (4 h/CO2 stream);;	96%
In neat (no solvent) 250°C (16 h/sealed tube);;	94%

: 7791-25-5
sulfuryl dichloride

: cadmium(II) sulphide

A: 7446-09-5
sulfur dioxide

B: 7704-34-9
sulfur

C: 10108-64-2
cadmium(II) chloride

Conditions

Conditions	Yield
3-4 h at 350°C in a sealed bombe tube;	A n/a B n/a C 95%
3-4 h at 350°C in a sealed bombe tube;	A n/a B n/a C 95%
16 h at 250°C in a sealed bombe tube;	A n/a B n/a C 94%

: (C2F5)2Cd*2(CH2)4SO2

: 10025-91-9
antimony(III) chloride

A: 34837-31-5
Sb(C2F5)3

B: 10108-64-2
cadmium(II) chloride

Conditions

Conditions	Yield
In sulfolane N2 atm.; stirring (4-5 d, 60°C); distn. (vac., 50°C); elem. anal.;	A 94% B n/a

: Cd(n-C4F9)2

: 10025-91-9
antimony(III) chloride

A: 194549-83-2
Sb(C4F9)3

B: 10108-64-2
cadmium(II) chloride

Conditions

Conditions	Yield
In sulfolane N2 atm.; stirring (4-5 d, 60°C); distn. (vac., 80°C); elem. anal.;	A 76% B n/a

: cadmium(II) selenide

: 7791-25-5
sulfuryl dichloride

A: 10026-03-6
selenium tetrachloride

B: 10025-68-0
diselenium dichloride

C: 10108-64-2
cadmium(II) chloride

Conditions

Conditions	Yield
SO2Cl2 vapor diluted with CO2, 2.5h at 280-290°C;	A n/a B n/a C 71%
SO2Cl2 vapor diluted with CO2, 2.5h at 280-290°C;	A n/a B n/a C 71%
SO2Cl2 vapor diluted with CO2, 5h in room temp., then short heating at 180-190°C;	A n/a B n/a C 60%
SO2Cl2 vapor diluted with CO2, 5h in room temp., then short heating at 180-190°C;	A n/a B n/a C 60%

: 10049-04-4, 25052-55-5
chlorine dioxide

: 7440-43-9
cadmium

A: cadmium chlorite

B: cadmium chlorate

C: cadmium(II) oxide

D: 10108-64-2
cadmium(II) chloride

Conditions

Conditions	Yield
In water The formed CdCl2 behaves as catalyst in the reaction.;	A 66% B 7% C 19% D 8%
In water The formed CdCl2 behaves as catalyst in the reaction.;	A 66% B 7% C 19% D 8%

...Expand

: 12107-04-9
dicarbonyl(cyclopentadienyl)iron(II) chloride

: 7440-43-9
cadmium

A: 38117-54-3
cyclopentadienyl iron(II) dicarbonyl dimer

B: (dicarbonylcyclopentadienyliron)cadmium chloride

C: 10108-64-2
cadmium(II) chloride

Conditions

Conditions	Yield
In tetrahydrofuran (Ar); at 20°C; sepd., evapd., treated with Et2O, sepd., concd. (vac.), pentane added at-5°C, washed (cold pentane), dried (vac.); elem. anal.;	A 14% B 53.6% C 20.6%

: 10025-91-9
antimony(III) chloride

: 104698-09-1
Cd(C6F13)2

A: Sb(C6F13)3

B: 10108-64-2
cadmium(II) chloride

Conditions

Conditions	Yield
In acetonitrile N2 atm.; stirring (4-5 d, 60°C), pptn.; filtn., washing (CH3CN), extraction (pentane), distn.; elem. anal.;	A 52% B n/a

: 15989-98-7
bis(pentafluorophenyl)cadmium

: 10025-82-8
indium(III) chloride

A: In(3+)*3C6F5(1-)*CH3CN=In(C6F5)3*CH3CN

B: 10108-64-2
cadmium(II) chloride

Conditions

Conditions	Yield
In acetonitrile byproducts: C6F5H; N2 atm.; heating (-30 to 0°C), stirring (24 h, room temp.), refluxing; evapn., extraction (n-pentane), evapn.; elem. anal.;	A 42.7% B n/a

: 15989-98-7
bis(pentafluorophenyl)cadmium

: 10025-82-8
indium(III) chloride

A: In(3+)*3C6F5(1-)*CH3OCH2CH2OCH3=In(C6F5)3*CH3OCH2CH2OCH3

B: 10108-64-2
cadmium(II) chloride

Conditions

Conditions	Yield
In further solvent(s) byproducts: C6F5H; N2 atm.; glyme, heating (-30 to 0°C), stirring (24 h, room temp.), refluxing; evapn., extraction (n-pentane), evapn.;	A 34.7% B n/a

CADMIUM CHLORIDE Chemical Properties

Molecular Structure of CADMIUM CHLORIDE(10108-64-2):

IUPAC Name: dichlorocadmium
Molecular Formula:CdCl₂
Molecular Weight:183.317000 g/mol
Appearance:milky White free flowing crystalline powder
Melting Point:568 °C(lit.)
Boiling Point:960 °C
Density:4.047 g/cm³
Solubility:soluble in acetone, alcohol, insoluble in ether
Water Solubility:100 g/100 mL (0 °C), 135 g/100 mL (20 °C), 147 g/100 mL (100 °C)
Sensitive:Hygroscopic
Vapor Density:6.3 (vs air)
Vapor Pressure:10 mm Hg (656 °C)
EINECS:233-296-7
Synonyms of CADMIUM CHLORIDE(10108-64-2):
Caddy;Cadmium chloride (CdCl2);Cadmium turf fungicide;cadmiumchloride(cdcl2);cadmiumchloride,anhydrous;CdCl2;Dichlorocadmium;Kadmiumchlorid
Categories of CADMIUM CHLORIDE(10108-64-2):
Inorganics;Analytical Reagents for General Use;C-D, Puriss p.a. ACS;Puriss p.a. ACS;Cadmium Salts;CadmiumMetal and Ceramic Science;Catalysis and Inorganic Chemistry;Chemical Synthesis;Crystal Grade Inorganics;Salts;Metal and Ceramic Science

CADMIUM CHLORIDE Uses

CADMIUM CHLORIDE(10108-64-2) is used for the preparation of cadmium sulfide. It is also used for photocopying, dyeing and electroplating.

CADMIUM CHLORIDE Production

CADMIUM CHLORIDE(10108-64-2) can be made by the action of anhydrous chlorine or hydrogen chloride gas on heated cadmium metal.
Cd(s) + 2 HCl(g) → CdCl₂(s) + H₂(g)

CADMIUM CHLORIDE Toxicity Data With Reference

1.	dni-hmn:hla 250 µmol/L	MUREAV Mutation Research. 92 (1982),427.
2.	cyt-ofs-mul 630 µg/L/4 W-C	BECTA6 Bulletin of Environmental Contamination and Toxicology. 36 (1986),199.
3.	orl-wmn LDLo:3 g/kg:BPR,GIT	BMJOAE British Medical Journal. 292 (1986),1559.
4.	orl-rat LD50:88 mg/kg	AFDOAQ Association of Food and Drug Officials of the United States, Quarterly Bulletin. 15 (1951),122.
5.	ipr-rat LD50:1800 µg/kg	EVHPAZ EHP, Environmental Health Perspectives. Subseries of DHEW Publications. 28 (1979),89.
6.	orl-mus LD50:60 mg/kg	APTOA6 Acta Pharmacologica et Toxicologica. 48 (1981),108.
7.	ihl-mus LC50:2300 mg/m3	NTIS** National Technical Information Service. (Springfield, VA 22161) (Formerly U.S. Clearinghouse for Scientific and Technical Information) PB158-508 .
8.	ipr-mus LD50:9300 µg/kg	NEZAAQ Nippon Eiseigaku Zasshi. Japanese Journal of Hygiene. 32 (1977),472.
9.	scu-mus LD50:3200 µg/kg	APTOA6 Acta Pharmacologica et Toxicologica. 48 (1981),108.
10.	ivn-mus LD50:3500 µg/kg

CADMIUM CHLORIDE Consensus Reports

NTP 10th Report on Carcinogens. IARC Cancer Review: Group 1 IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 58 , 1993,p. 119.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) ; Animal Sufficient Evidence IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 2 , 1973,p. 74.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) ; Animal Sufficient Evidence IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 11 , 1976,p. 39.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) ; Human Sufficient Evidence IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 58 , 1993,p. 119.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) ; IARC Cancer Review: Animal Sufficient Evidence IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 58 , 1993,p. 119.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) ; EPA Genetic Toxicology Program. Cadmium and its compounds are on the Community Right-To-Know List. Reported in EPA TSCA Inventory.

CADMIUM CHLORIDE Safety Profile

The safety information of CADMIUM CHLORIDE(10108-64-2) is as follows:
Hazard Codes:T,T+ ,N
Risk Statements:45-46-60-61-25-26-48/23/25-51/53-50/53-48/20/22-23-22
45:May cause cancer
46:May cause heritable genetic damage
61:May cause harm to the unborn child
25:Toxic if swallowed
26:Very toxic by inhalation
48/23/25:Toxic : danger of serious damage to health by prolonged exposure through inhalation and if swallowed
51/53:Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
50/53:Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
48/20/22:Harmful: danger of serious damage to health by prolonged exposure through inhalation and if swallowed
22:Harmful if swallowed
23:Toxic by inhalation
Safety Statements:53-45-61-60-36/37-28
53:Avoid exposure - obtain special instructions before use
45:In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible)
60:This material and its container must be disposed of as hazardous waste
61:Avoid release to the environment. Refer to special instructions/safety data sheets
36/37:Wear suitable protective clothing and gloves
28:After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer)
RIDADR:UN 3082 9/PG 3
WGK Germany:3
RTECS:EV0175000
F:3-9-23
HazardClass:6.1
PackingGroup:III
Confirmed human carcinogen with experimental carcinogenic and tumorigenic data. Poison by ingestion, inhalation, skin contact, intraperitoneal, subcutaneous, intravenous, and possibly other routes. Human systemic effects by ingestion: blood pressure, acute pulmonary edema, hypermotility, diarrhea. Experimental teratogenic and reproductive effects. Human mutation data reported. Reacts violently with BrF₃ and K. When heated to decomposition it emits very toxic fumes of Cd and Cl⁻. See also CADMIUM COMPOUNDS and CHLORIDES.

CADMIUM CHLORIDE Standards and Recommendations

OSHA PEL: TWA 5 μg(Cd)/m³
ACGIH TLV: TWA 0.002 mg(Cd)/m³ (respirable dust), Suspected Human Carcinogen); BEI: 5 μg/g creatinine in urine; 5 μg/L in blood
DFG MAK: Animal Carcinogen, Suspected Human Carcinogen
NIOSH REL: (Cadmium) Reduce to lowest feasible level

CADMIUM CHLORIDE Specification

First aid measures of CADMIUM CHLORIDE(10108-64-2):
Eyes:Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin Get medical aid immediately. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:Get medical aid immediately. Wash mouth out with water.
Inhalation:Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.

Storage Information of CADMIUM CHLORIDE(10108-64-2):
Keep away from sources of ignition. Store in a cool, dry place. Do not store in direct sunlight. Store in a tightly closed container. Keep under a nitrogen blanket.

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