- SITE SELECTIVITY IN THE REACTIONS OF 1,3-DIPOLES AND DIENES WITH TETRACYCLO2,10.03,6>DODECA-4,8,11-TRIENE
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1,3-Dipoles and dienes reacted smoothly with excess tetracyclo2,10.03,6>dodeca-4,8,11-triene (1) to give good yields of monoadducts in a highly selective reaction.The attack by 1,3-dipoles and dienes to 1 occurred only at the
- Burdisso, M.,Gamba, A.,Gandolfi, R.,Pevarello, P.
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p. 4355 - 4360
(2007/10/02)
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- N-Phenyltriazolinedione Adducts of Bicyclodecatetraene and Tricyclo2,8>decatriene(Bullvalene)
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Bicyclodecatetraene (1) and bullvalene (8) generate cycloadducts 3 and 9 with N-phenyltriazolinedione (2).Base-induced hydrolysis and subsequent oxidation give tetracyclic and tricyclic azo compounds 6 and 12, respectively. 6 has a half-life of ca.
- Joesel, Rainer,Schroeder, Gerhard
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p. 1428 - 1437
(2007/10/02)
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