Synthetic studies towards bridgehead diprenyl-substituted bicyclo[3.3.1]nonane-2,9-diones as models for polyprenylated acylphloroglucinol construction
The synthesis of bridgehead diprenylated bicyclo[3.3.1]-nonane-2,9-dione, based on a reductive rearrangement of an enol lactone, is presented. The same target could be reached by a one-step sequence involving Michael addition of 2,6-diprenylcyclohexanone
Pouplin, Thomas,Tolon, Blanca,Nuhant, Philippe,Delpech, Bernard,Marazano, Christian
p. 5117 - 5125
(2008/03/18)
Cyclooctane or Cyclohexane Annulations Based on Intramolecular Additions of Allylsilanes to Conjugated Dienones
The scope and limitations of alkenyl dienone cyclizations for the formation of fused cyclooctane or cyclohexane systems are described.
Majetich, George,Hull, Kenneth,Casares, Ada M.,Khetani, Vikram
p. 3958 - 3973
(2007/10/02)
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