Reactions of dibenzoyldiazene. Part 1. Cycloaddition and the inhibition and retardation of vinyl addition polymerizations
The cycloaddition of dibenzoyldiazine to a selection of monomers with electron-rich vinyl groups has been shown to compette with its capability as an inhibitor of their polymerization by a free-radical mechanism.Cycloaddition to monomers with electron-deficient vinyl groups does not occur, and dibenzoyldiazene acts solely as a retarder of their polymerization.Kinetic mechanisms compatible with the experimental observations are proposed.
Bassam, Farideh,Jones, Richard G.
p. 1759 - 1766
(2007/10/02)
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