The reactivity of unsubstituted 1,2,3-triazine was investigated using various nucleophilic and electrophilic reagents, molecular orbital calculations, and low temperature nmr measurements.
The Reaction of 1,2,3-Triazines with Grignard Reagents
Monocyclic 1,2,3-triazines reacted with Grignard reagents to form adducts due to N-2 and C-5 attack together with β-substituted acrylaldehydes and N-substituted pyrazoles; the results show that the N-2, C-4, and C-5 positions are reactive towards Grignard reagents.
Ohsawa, Akio,Kaihoh, Terumitsu,Igeta, Hiroshi
p. 1370 - 1371
(2007/10/02)
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