- PALLADIUM COMPLEXES IN THE HYDROSILYLATION OF ACETYLENE
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The catalytic activities of triphenylphosphine-, trialkylphosphine-, and acetylacetone-palladium complexes in the hydrosilylation of acetylene with trichloro-, alkyldichloro-, triethyl, and triethoxy-silanes were investigated.The yields of the corresponding (triorganylsilyl)ethylenes and 1,2-bis(triorganylsilyl)ethanes (conditions: 70-80 deg C, solvent xylene) depend on the nature of the ligands on the palladium atom and the character of the substituents on the silicon atom in the hydride silane.
- Kopylova, L. I.,Pukhnarevich, V. B.,Voronkov, M. G.
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p. 276 - 278
(2007/10/02)
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