Cross-metathesis assisted by microwave irradiation
Microwave irradiation effectively accelerates cross-coupling metathesis reactions between deactivated olefins. Reactions have been carried out with the phosphine-free Hoveyda-Grubbs catalyst and the "second generation Grubbs' catalyst." While there have been reports that a "microwave effect" is observed in various transformations, the accelerations we observe are due to the efficient and rapid heating and increased pressure in the microwave apparatus.
Bargiggia, Frederic C.,Murray, William V.
p. 9636 - 9639
(2007/10/03)
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