Facile rearrangement of N4-(α-aminoacyl)cytidines to N-(4-cytidinyl)amino acid amides
Under near neutral and mildly basic conditions, primary N4-(α-aminoacyl)cytidines (4a-g) undergo a facile rearrangement to form N-(4-cytidinyl)amino acid amides (5a-g). Secondary aminoacyl derivatives rearrange with other competing pathways. Tertiary aminoacyl derivatives do not rearrange.
Zhang, Deyi,Bender, David M.,Victor, Frantz,Peterson, Jeffrey A.,Boyer, Robert D.,Stephenson, Gregory A.,Azman, Adam,McCarthy, James R.
p. 2052 - 2055
(2008/09/18)
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