Enantioselective synthesis of arylglycine derivatives by direct C-H oxidative cross-coupling
A new method for the synthesis of chiral α-amino acid derivatives by enantioselective C-H arylation of N-aryl glycine esters with aryl boric acids in the presence of a chiral Pd(ii)-catalyst has been developed. This work successfully integrates the direct C-H oxidation with asymmetric arylation and exhibits excellent enantioselectivity. This journal is
Phosphorylation of Glycine Derivatives via Copper(I)-Catalyzed Csp3?H Bond Functionalization
A simple and efficient one-pot approach has been developed for a copper-catalyzed phosphorylation of glycine derivatives under air and at room temperature. The present cross-dehydrogenative coupling allows various methoxyphenyl-protected glycine derivativ
A 4 - phenyl quinoline compound, preparation method and application thereof (by machine translation)
The invention discloses a 4 - phenyl quinoline compound, its preparation method and application, the invention of the 4 - phenyl quinoline compound to, its structure (I) shown in the diimmonium: Wherein R1 Is - OH, - Cl, - OCH3 Or -
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Paragraph 0055
(2017/08/31)
Copper Triflate Catalyzed Oxidative α-Allylation of Glycine Derivatives
Copper triflate catalyzed oxidative C-H functionalization of glycine derivatives with allyltributyltin has been established using oxygen or tert -butyl hydroperoxide as oxidant. Various glycine esters and glycine amides were suitable substrates for this oxidative allylation reaction and afforded the desired homoallylic amines in moderate to good yields.
Chen, Ting-Ting,Cai, Chun
supporting information
p. 1368 - 1372
(2017/06/27)
Functionalizing glycine derivatives by direct C-C bond formation
(Chemical Equation Presented) Come on glycine: Two different types of glycine derivatives are α-functionalized using cross-dehydrogenative- coupling (CDC) reactions. The method allows the efficient attachment of a malonate or aromatic alkyne group on the α-position of the glycine derivatives under very mild conditions.
Zhao, Liang,Li, Chao-Jun
supporting information; experimental part
p. 7075 - 7078
(2009/04/07)
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