- ω-alkyne-mono- and diphosphonates - Synthesis and sonogashira cross-coupling reaction with aryl halides
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A convergent approach to functionalise aromatic compounds with a linker terminated by a phosphonate group is reported. The starting point of this strategy is the synthesis of five new ω-alkyne-phosphonates. The linker between the phosphonate group and the alkyne part is either an alkyl or an ether chain. This strategy is based on the use of the phosphonate group as the anchoring point for the attachment of organic compounds onto alumina and the alkyne group, which is used to functionalise aryl halide compounds by a Sonogashira cross-coupling. The use of 1,10-phenanthroline as substrate illustrates the application of this strategy to an aromatic ligand. Wiley-VCH Verlag GmbH & Co. KGaA, 2007.
- Delain-Bioton, Lise,Villemin, Didier,Jaffres, Paul-Alain
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p. 1274 - 1286
(2008/09/18)
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- Polydiacetylenes in organic-inorganic hybrid systems
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Mono- and di-ammonium chloride salts with butadiyne moieties were synthesized and they were combined with cadmium chloride in thin film forms. Layered perovskite structures were confirmed for spin-coated films of bis(10,12-nonadecadiynylammonium)tetrachlorocadmate 26 and bis(10,12- heptacosadiynylammonium)tetrachlorocadmate 27 and Langmuir-Blodgett films of 27. After UV irradiation, blue-colored polydiacetylene incorporated in the layered perovskite structure was obtained for the spin-coated films of 27.
- Kosuge, Hiroaki,Okada, Shuji,Oikawa, Hidetoshi,Nakanishi, Hachiro
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- Preparation of cycloalkylacetylene compounds using dialkylaminomagnesium halide or bis(dialkylamino)magnesium
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The process of invention reacts an alkynyl halide with a mixture that includes a dialkylaminomagnesium halide or a bis(dialkylamino)magnesium compound to produce a cycloalkylacetylene compound. Preferably, the dialkylaminomagnesium halide compound is of the general formula R 2 NMgX (where R is a linear, branched, or cyclic alkyl substituent or R 2 N represents a heterocyclic alkyl amine and X is Cl, Br, or I) and the bis(dialkylamino)magnesium compound is of the general formula (R 2 N) 2 Mg (where R is a linear, branched, or cyclic alkyl substituent or R 2 N represents a heterocyclic alkylamine). In a preferred method of the invention, the reaction is conducted at moderate temperatures for a period of about 12 to 24 hours. The reaction mixture preferably includes tetrahydrofuran (THF), or a hydrocarbon, or a hydrocarbonether mixture. The preferred compounds produced by this process are cycloalkylacetylene compounds having 5 to 20 carbons, such as cyclopropylacetylene and cyclobutylacetylene.
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