Reaction of N-fluoropyridinium fluoride with isonitriles: A convenient route to picolinamides
Reaction of N-fluoropyridinium fluoride generated in situ with a series of isonitriles led to the formation of the corresponding picolinamides in good yields. A similar reaction sequence for quinoline yielded the respective derivatives of 2-quinoline carboxylic acid. The proposed reaction mechanism involves the intermediate formation of a highly reactive carbene species.
Kiselyov, Alexander S.
p. 2279 - 2282
(2007/10/03)
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