cas 10558-25-5, 4-Bromo-3,5-dimethylisoxazole | Articles data ｜lookchem

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10558-25-5

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Sokolov,Egorova
(1974)
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Orthogonal Stability and Reactivity of Aryl Germanes Enables Rapid and Selective (Multi)Halogenations
While halogenation is of key importance in synthesis and radioimaging, the currently available repertoire is largely designed to introduce a single halogen per molecule. This report makes the selective introduction of several different halogens accessible. Showcased here is the privileged stability of nontoxic aryl germanes under harsh fluorination conditions (that allow selective fluorination in their presence), while displaying superior reactivity and functional-group tolerance in electrophilic iodinations and brominations, outcompeting silanes or boronic esters under rapid and additive-free conditions. Mechanistic experiments and computational studies suggest a concerted electrophilic aromatic substitution as the underlying mechanism.
Deckers, Kristina,Fricke, Christoph,Schoenebeck, Franziska
supporting information
p. 18717 - 18722
(2020/08/25)

AGONISTS OF GPR40
The present invention relates to compounds that have the ability to modulate the activity of GPR40 and are there-fore useful in the treatment of GPR40 related disorders. In addition the invention relates to the compounds, methods for their preparation, pharmaceutical compositions containing the compounds and the uses of these compounds in the treatment of certain disorders related to GPR40 activity.
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Page/Page column 148; 149

(2012/02/05)

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300-87-8
3,5-dimethyl-1,2-oxazole

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Chemical Properties

Appearance/Colour :clear colorless to light yellow liquid
Melting Point: 176ºC(lit.)
Boiling Point: 215.149 °C at 760 mmHg
Flash Point:83.919 °C
Density: 1.541 g/cm³
Storage Temp.:Keep Cold
Vapor Pressure: 0.219mmHg at 25°C
Refractive Index: n20/D 1.486(lit.)
PKA: -2.35±0.28(Predicted)
Sensitive: Light Sensitive
BRN: 108522
PSA: 26.03000
LogP: 2.05390

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