- Trifluoromethanesulfonato derivatives of ruthenium(II)
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The reactivity of Ru(O2CNiPr2) 2(CO)2(PPh3)2 (1), towards CF 3SO3H (TfOH, trifloromethanesulfonic acid or triflic acid) has been studied and the products [R
- Dell'Amico, Daniela Belli,Calderazzo, Fausto,Grazzini, Andrea,Labella, Luca,Marchetti, Fabio
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p. 411 - 418
(2008/10/08)
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- Complexes of the Platinum Metals. Part 33. Synthesis of Some Ruthenium and Osmium Sulphonate Derivatives: X-Ray Crystal Structure of Aqua(carbonyl)bis(toluene-p-sulphonato)bis(triphenylphosphine)ruthenium(II)
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Sulphonic acids RSO3H (R=CH3, CF3, or C6H4CH3-p) react with the precursors (M=Ru or Os) and or in refluxing benzene or toluene to afford the complexes and respectively.The precursors and react with sulphonic acids in refluxing benzene to give the η6-benzene complexes 6-C6H6)(PPh3)2>.However a similar reaction in refluxing ethanol yielded .The complexes have been shown by variable-temperature 1H and 31P- n.m.r. spectroscopy to be fluxional in solution.The solid-state structure of one example, has been determined by X-ray diffraction methods.The crystals are monoclinic, space group P21/n, with a=24.382(5), b=18.075(4), c=10.729(2) Angstroem, β=99.03(2) grad, and Z=4.The octahedral ruthenium(II) complex contains monodentate sulphonate ligands (trans to PPh3 and CO) and an aqua ligand (trans to PPh3) with strong hydrogen-bonding interactions between the H atoms of the H2O and the non-co-ordinated oxygen atoms of the sulphonate ligands.The molecular structure is very similar to that previously reported for the alcohol dehydrogenation catalyst .
- Harding, Alexander P.,Robinson, Stephen D.,Henrick, Kim
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p. 415 - 420
(2007/10/02)
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