- Method for synthesizing glycol phenyl ether methacrylate (by machine translation)
-
Compared with a traditional esterification reaction, the ethylene glycol phenyl ether methacrylate has the advantages of being high in catalytic activity, less in side reaction, simple in post-treatment, free of waste water, small in environmental pollution and high in product yield, and belongs to the sustainable development green chemical engineering process. The method has the advantages of high catalytic activity, low side reaction, simple post-treatment, no wastewater generation, low environmental pollution and high yield. 94.44percent 91.36percent. (by machine translation)
- -
-
Paragraph 0030-0063
(2020/08/27)
-
- Chemoselective Transesterification of Acrylate Derivatives for Functionalized Monomer Synthesis Using a Hard Zinc Alkoxide Generation Strategy
-
A new practical method for the synthesis of functionalized acrylate derivatives with the view to prepare functional polymers was explored. Hard zinc alkoxide generation enabled the highly chemoselective transesterification of acrylate derivatives over the undesired conjugate addition, which caused polymerization. The combined use of the catalytic zinc cluster Zn4(OCOCF3)6O and 4-(dimethylamino)pyridine delivered various functionalized acrylate derivatives through the transesterification of commercially available methyl acrylate derivatives with functionalized alcohols under mild conditions.
- Nakatake, Daiki,Yazaki, Ryo,Ohshima, Takashi
-
supporting information
p. 3696 - 3699
(2016/08/20)
-