An ion-pair template for rotaxane formation and its exploitation in an orthogonal interaction anion-switchable molecular shuttle
(Chemical Equation Presented) Chloride control: The serendipitous discovery of a molecular recognition motif that is triggered by the formation of an anion-palladium coordination bond is exploited as an efficient rotaxane-forming template and as the basis of a molecular shuttle. The macrocycle of this rotaxane moves between the two stations when the counterion is changed from chloride to hexafluorophosphate (see picture).
Barrell, Michael J.,Leigh, David A.,Lusby, Paul J.,Slawin, Alexandra M. Z.
p. 8036 - 8039
(2009/04/13)
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