CARBOPALLADATION DES ALKYLIDENECYCLOPROPANES-I; CAPTURE INTERMOLECULAIRE DE L'ORGANOPALLADIQUE INTERMEDIAIRE
The reaction of methylenecyclopropane and 1-cyclopropylidene pentane with iodobenzene or 2-bromopropene and a delocalized anion (issued from malonate or from a β-sulfonyl ester) in the presence of catalytic amounts of a palladium (0) complex leads to conj
Fournet, Guy,Balme, Genevieve,Gore, Jacques
p. 5809 - 5820
(2007/10/02)
CARBOPALLADATION DES ALKYLIDENECYCLOPROPANES. OBTENTION DE DIENES-1,3 ET DE STYRENES FUNCTIONNALISES.
The palladium(o) catalyzed reaction of iodo-benzene and 2-bromopropene with methylene and n-pentylidenecyclopropane in the presence of sodium methyl malonate leads, via a ?-allyl palladium complex, to styrenes and 1,3-butadienes derivatives 2 and 3.
Balme, Genevieve,Fournet, Guy,Gore, Jacques
p. 3855 - 3858
(2007/10/02)
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