cas 110193-49-2, (R)-5-(3-Hydroxyphenyl)-3-methyl-2-oxazolidinone | Articles data ｜lookchem

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110193-49-2

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Whole-cell yeast-mediated preparation of (R)-2-chloro-1-(3-nitrophenyl) ethanol as a synthetic precursor for (R)-phenylephrine
The incubated whole-cell biocatalyst of Pichia minuta JCM 3622 reduced 2-chloro-1-(3-nitrophenyl)ethanone to provide (R)-2-chloro-1-(3-nitrophenyl) ethanol with 99.2% ee in 87% isolated yield in the presence of Amberlite XAD-7 as a reservoir for the hydrophobic, crystalline and toxic substrate. The product was transformed to (R)-1-(3-hydroxyphenyl)-2-methylaminoethanol (phenylephrine, 1a), a selective α1-adrenergic receptor agonist, in 98.0% ee over five steps.
Tokoshima, Daisuke,Hanaya, Kengo,Shoji, Mitsuru,Sugai, Takeshi
p. 95 - 99
(2013)
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Phenylephrine Derivatives as Leukotriene D4 Antagonists
Two series of phenylephrine derivatives were prepared and tested as inhibitors of leukotriene D4 (LTD4) induced and ovalbumin-induced bronchospasm in the guinea pig.The most potent compound of the urea series, (R)-N,N-diethyl-N-2-hy
Musser, John H.,Kubrak, Dennis M.,Bender, Reinhold H. W.,Kreft, Anthony F.,Nielsen, Susan T.,et al.
p. 2087 - 2093
(2007/10/02)

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Chemical Properties

Appearance/Colour :oil
Boiling Point: 447.638 °C at 760 mmHg
Flash Point:224.524 °C
Density: 1.289 g/cm³
Solubility:Dichloromethane
Refractive Index: 1.584
PSA: 49.77000
LogP: 1.45320

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