Catalytic behaviour of chloroperoxidase from Caldariomyces fumago in the oxidation of cyclic conjugated dienes
Chloroperoxidase from Caldariomyces fumago has been investigated as a catalyst for the oxidation of cyclic conjugated dienes. The nature of the substituents and the size of the carbocycle affect the enantioselectivity of the enzyme. An unexpected course o
Sanfilippo, Claudia,Nicolosi, Giovanni
p. 1889 - 1892
(2007/10/03)
?-Facial diastereoselectivity in the Diels-Alder reactions of cis-cyclohexa-3,5-diene-1,2-diol and derivatives with N-phenylmaleimide
N-Phenylmaleimide undergoes Diels-Alder cycloaddition predominantly to the face of cis-cyclohexa-2,4-diene-1,2-diol (3) syn to the oxygen functions.Derivatization can be used to alter the ?-facial diastereoselectivity in a synthetically useful manner.The
Gillard, James R.,Burnell, D. Jean
p. 1296 - 1307
(2007/10/02)
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