Lewis acid-catalyzed coupling reactions of allyl trimethylsilyl ethers with allylsilanes
For the simultaneous preparation of molecules having both the nucleophilic and electrophilic sites, allyl trimethylsilyl ethers as electrophilic allylating reagents are studied. Allyl trimethylsilyl ethers react with allyl trimethylsilanes in the presence
Yokozawa,Furuhashi,Natsume
p. 5243 - 5246
(2007/10/02)
A Facile Synthesis of 1,5-Dienes and β,γ-Unsaturated Nitriles via Trityl Perchlorate-Catalyzed Allylation
In the presence of a catalytic amount of trityl perchlorate, secondary and tertiary allyl ethers smoothly react with allylsilanes and silyl cyanide to give the corresponding 1,5-dienes and β,γ-unsaturated nitriles, respectively, in good yields.