Thermal Decomposition and Cobalt-Carbon Bond Dissociation Energies of Organocobalamins: Neopentyl-, (Cyclopentylmethyl)-, (Cyclohexylmethyl)-, (Tetrahydrofurfuryl)- and ((Tetrahydro-2H-pyryl)methyl)cobalamin
The title compounds were prepared and characterized and their thermal decomposition reactions were studied in aqueous solutions of varying pH and containing varying concentrations of cob(II)alamin (B12) and of bis(dimethylglyoximato)cobalt(II), .
Kim, Sook-Hui,Chen, Hui Lan,Feilchenfeld, Natalie,Halpern, Jack