The 'inverse electron-demand' Diels-Alder reaction in polymer synthesis. Part 5: Preparation and model reactions of some electron-rich bis-dienamines
The m- and p-phenylene-bridged bis-azolopyridinium salts have been synthesized and converted into the corresponding bis-dienamines by reaction with pyrrolidine. These dienamines react readily with dimethyl 1,2,4,5-tetrazine-dicarboxylate to yield the bis-azolylvinyl-pyridazines.
Kotschy, András,Faragó, János,Csámpai, Antal,Smith, David M.
p. 3421 - 3425
(2007/10/03)
CYCLOPALLADATION TO FORM PLANAR TRIDENTATE (-) INTRAMOLECULAR COORDINATION SYSTEMS INVOLVING PYRIDINE DONOR GROUPS, INCLUDING LIGAND SYNTHESIS AND X-RAY STRUCTURAL STUDIES
Reaction of palladium(II) acetate with 1,3-bisbenzene and 1,3-bis(2-pyridinecarbonyl)benzene results in cyclopalladation and formation of 2,6-bisphenyl and 2,6-bis(2-pyridinecarbonyl)phenyl complexes PdNC5H4
Canty, Allan J.,Minchin, Nigel J.,Skelton, Brian W.,White, Allan H.
p. 1477 - 1484
(2007/10/02)
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