Use of the Wadsworth-Emmons reaction for preparing hindered vinyl ethers and related 1,2-dioxetanes
Arylaldehyde acctals can be reacted with trimethyl phosphite to produce the corresponding dimethyl α-methoxy-benzylphosphonates, themselves used in a Wadsworth-Emmons reaction with adamantanone to produce hindered methyl vinyl ethers. These vinyl ethers are useful in the preparation of chemiluminescent 1,2-dioxetanes. The scope of the reaction has been explored.
Roeschlaub, Carl A.,Sammes, Peter G.
p. 2243 - 2248
(2007/10/03)
Face Selection in the Capture of Anionic Carbon
Several reactions of 2-(5-phenyladamantyl) derivatives have been examined with the objective of determining the stereochemistry of addition of electrophiles to a trigonal center C2 carrying a full or partial negative charge.These reactions included the ca
Bodepudi, Vani R.,Noble, William J. le
p. 3265 - 3269
(2007/10/02)
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