Oxidative Cycloaddition of 1,3-Diketone and Olefin Using Electroorganic Chemistry
The electrochemical oxidation of 1,3-diketones and 2-substituted 1,3-diketones in the presence of olefin gave the cycloadducts, dihydrofuran and tetrahydrofuran derivatives, respectively.A mechanism involving electrooxidative formation of the radical intermediate from the diketone followed by addition to the olefin has been proposed.
OXIDATIVE CYCLOADDITION OF 1,3-DIKETONE AND OLEFIN USING ELECTROORGANIC CHEMISTRY
Electrochemical oxidation of 1,3-diketones in the presence of olefins afforded the formal cycloaddition products, dihydrofuran derivatives or tetrahydrofuran derivatives.A mechanism involving attack of a radical intermediate to an olefin has been proposed.