OXIDATION OF 2,6-DI-tert-BUTYL-4-METHYLPHENOL BY OXYGEN IN AQUEOUS AMMONIA SOLUTION
Both monomeric and dimeric oxidation products are formed during the oxidation of 2,6-di-tert-butyl-4-methylphenol (ionole) by oxygen in a water-propanol solution of ammonia.Two nitrogen-containing compounds 3,3'-5,5'-tetra-tert-butylindophenol and 2,6-di-tert-butyl-4-cyanophenol are also formed, and their amounts in the reaction mixture increase with increase in temperature (45-120 deg C).
Fedulina, T. G.,Deineko, I. P.,Zenkevich, I. G.,Zarubin, M. Ya.
p. 1373 - 1377
(2007/10/02)
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