- Synthesis of sphingadienine-type glucocerebrosides
-
Sphinga-4,8-dienine derivatives were synthesized from a vinyl-epoxide 5 via three routes. First, reaction of 5 with 2-dodecenyl cyanocuprate afforded a 1:1 mixture of (4E,8E)- and (4E,8Z)-sphingadienine derivatives in high yield. Second, the (4E,8E)-isome
- Murakami, Teiichi,Shimizu, Toshimi,Taguchi, Kazuhiro
-
p. 533 - 545
(2007/10/03)
-
- Sphingolipids and glycerolipids. IV. Syntheses and ionophoretic activities of several analogues of soya-cerebroside II, a calcium ionophoretic sphingoglycolipid isolated from soybean
-
For examination of the structure-activity relationship five analogues [(2'R)-2'-hydroxypalmitoyl (3), palmitoyl (4), (2'S)-2'-hydroxypalmitoyl (5), β-D-galactosyl (6), and 8,9-dihydro (7) relevancies] of soya-cerebroside II (2), which is a calcium ionopho
- Shibuya,Kurosu,Minagawa,Katayama,Kitagawa
-
p. 1534 - 1544
(2007/10/02)
-
- Synthesis of Sphingosine Relatives, VII. - Synthesis fo Anti-Ulcerogenic Cerebrosides Isolated from Tetragonia tetragonoides
-
The synthesis of (2S,3R,4E,8E,2'R)-1-O-(β-D-glucopyranosyl)-N-(2'-hydroxyhexadecanoyl)-4,8-sphingadienine (1a) and its (8Z) isomer (1b) was accomplished by employing (R)-2-aminohexadecanoic acid, D-glucose, and (S)-serine as chiral sources.
- Mori, Kenji,Kinsho, Takeshi
-
p. 807 - 814
(2007/10/02)
-