Facile synthesis of structurally diverse 5-oxopiperazine-2-carboxylates as dipeptide mimics and templates
A sequence of Michael addition of a primary amine onto methyl 2-chloro-2-cyclopropylidene-acetate (1), acylation of the adduct with α-bromo acid chlorides under modified Schotten-Baumann conditions and ring-closing twofold nucleophilic substitution on the
Limbach, Michael,Lygin, Alexander V.,Korotkov, Vadim S.,Es-Sayed, Mazen,De Meijere, Armin
supporting information; experimental part
p. 3338 - 3342
(2009/10/23)
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