Features of catalyzed hydration of 2-(dichloromethyl)-N-[(1R)-1- phenylethyl)]cyclopent-3-ene-1-carboxamides
The hydration of gem-dichloromethyl group in 2-(dichloromethyl)-N-[(1R)-1- phenylethyl)]cyclopent-3-ene-1-carboxamides in aqueous acetonitrile catalyzed by AgNO3, FeCl3?6H2O, PdCl2, and BaO was investigated. The optimum results were obtained at the use of BaO. It was demonstrated, that Pd-catalyzed reactions initiated intermolecular ether formation from the primary hydration products, bicyclic amides.
Gizametdinov,Miftakhov
experimental part
p. 694 - 697
(2009/12/05)
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