Studies on the oxidative N-demethylation of atropine, thebaine and oxycodone using a FeIII-TAML catalyst
The reaction pathway and selectivity of the oxidative N-demethylation of the alkaloid atropine with H2O2 using a Fe III-TAML catalyst has been investigated. The conversion of atropine in ethanol with aqueous H2O
Do Pham, Duy D.,Kelso, Geoffrey F.,Yang, Yuanzhong,Hearn, Milton T.W.
MEANS AND METHODS FOR THE N-DEALKYLATION OF AMINES
The invention relates to improved means and methods for N- dealkylation of alkylated amines. Provided is a method for the catalytic N- dealkylation of an N-alkylated amine substrate, comprising incubating said amine substrate in a suitable solvent in the
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Page/Page column 21
(2017/11/10)
ELECTRON-TRANSFER ACTIVATION. SALT EFFECTS ON THE PHOTOOXADIDATION OF TERTIARY AMINES : A USEFUL N-DEMETHYLATION METHOD
Photooxidation of tertiary methylamines sensitized by electron acceptors like 9,10-dicyanoanthracene is shown to proceed by two distinct ways depending on the presence of added salts.In the absence of added salt both nor and N-formyl compounds were obtained while with added salt the nor-derivative is obtained highly efficiently.
Santamaria, J.,Ouchabane, R.,Rigaudy, J.
p. 3977 - 3980
(2007/10/02)
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