CAPTO-DATIVE EFFECTS MEASURED BY AZO DECOMPOSITIONS
The activation parameters determined for rates of decomposition of compounds 3a-d indicate a substantial difference in free energies of activation, approximately 6 kcal/mol, and can be explained on the basis of capto-dative stabilization of the incipient radicals
Janousek, Zdenek,Bougeois, Jean-Luc,Merenyi, Robert,Viehe, Heinz G.,Luedtke, Alan E.,et al.
p. 3379 - 3382
(2007/10/02)
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