Radical Cyclization of Some Unsaturated Carbohydrate-Derived Acetals
Treatment of halogeno acetals derived from deoxy-D-hexenopyranosides of erythro and threo configuration with tributyltin hydride with a radical initiator gave fused pyranofuranosides.This allowed the completely stereo and regio-specific introduction of a
Moufid, Nadira,Chapleur, Yves,Mayon, Patrick
p. 991 - 998
(2007/10/02)
UNSATURATED CARBOHYDRATES. PART 29 THEIR APPLICATION TO THE SYNTHESIS OF STEREOSPECIFICALLY DOUBLY AND TRIPLY BRANCHED DERIVATIVES
Treatment of 2,3-dideoxy-α-D-erythro-hex-2-enopyranosyl derivatives having 2-haloethyl substituents separately at O-1 and O-4 with tri-n-butyltin hydride together with a radical initiator gave products 16 and 5,6 with tetrahydrofuranyl rings cis-fused to
Ferrier, Robert J.,Petersen, Paul M.
p. 1 - 12
(2007/10/02)
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