- Syntheses and reactivity of acetylide-containing clusters of Group 1B metals. VIII. Preparation, characterization and possible structure of a novel pentanuclear trimetallic cluster -. Reactions of pentanuclear and trinuclear acetylide complexes
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The novel pentanuclear trimetallic cluster - has been prepared by the reactions of - with a mixture of gold phenylacetylide and silver phenylacetylide, of - with n>, or of - with n>.Its possible structure is discussed.The conversion of the pentanuclear clusters - and - into the high polynuclearity trimetallic cluster - and of - into the complex - is described.The reactions of - with PPh3, P(OMe)3, and CuCl, and those of 2- with n>, a mixture of n> and n>, and CuCl are reported.
- Abu-Salah, Omar M.,Al-Ohaly, Abdel Razzak A.,Mutter, Ziad F.
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p. 267 - 273
(2007/10/02)
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- Syntheses and reactivity of acetylide-containing clusters of Group 1B Metals VII. Preparation and possible structures of the novel pentanuclear -,-,and - clusters. The reactivity of
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The stepwise synthesis of the gold-silver pentanuclear cluster - is described.The pentanuclear clusters - and - are obtained by the reactions of silver phenylacetylide with, respect
- Abu-Salah, Omar M.,Al-Ohaly, Abdel Razzak A.,Mutter, Ziad F.
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p. 427 - 434
(2007/10/02)
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- Syntheses and Reactivity of Acetylide-containing Clusters of Group 1B Metals. Stepwise Syntheses of Trinuclear - and Pentanuclear - and - Clusters
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The pentanuclear cluster - was obtained from the reaction between n> and a mixture of - and n>.Its structure is described.The same cluster has been synthesized in a stepwise manner starting with - through the binuclear complex - and the trinuclear cluster -.The synthesis of the analogous gold-silver cluster - was achieved by a slightly modified method.
- Abu-Salah, Omar M.,Al-Ohaly, Abdel Razzak A.
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p. 2297 - 2300
(2007/10/02)
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