- N,N′-dibenzyldithiooxamide
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The title compound, alternatively known as N,N′-dibenzylethanedithioamide, C16H16N2S2, lies about an inversion centre and contains a planar trans-dithiooxamide fragment characterized by a strong intramolecular hydrogen bond between the S atom and the adjacent amide H atom in the solid state, with an S...N distance of 2.926 (1) A. The aryl substituent is oriented orthogonal to the mean plane of the trans-dithiooxamide fragment due to steric hindrance and this effect is discussed.
- Bruno, Giuseppe,Lanza, Santo,Nicolo, Francesco,Tresoldi, Giuseppe,Rosace, Giuseppe
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- REACTIVITY OF CYANODITHIOFORMATE TOWARDS PRIMARY AMINES
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The two electrophilic carbon atoms of methyl cyanodithioformate 1 are able to react with primary amines giving a variety of different products depending upon the nature of amines.The one step reaction with o-dinucleophiles giving condensed heterocompounds in moderate to good yields is of interest.
- Diego, Carmen de,Gomez, Encarnacion,Avendano, Carmen
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p. 649 - 651
(2007/10/02)
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- STUDIES OF DIOXAMIDE AND DITHIO-OXAMIDE METAL COMPLEXES. PART 2. SYNTHESIS AND SPECTRAL CHARACTERISATION OF RNHC(S)C(S)NHR (R = ALKYL OR ARYL) COMPLEXES WITH SbX3 (X = Cl OR Br), BiCl3, SnX4 (X = Cl OR Br), AND TiCl4. CRYSTAL AND MOLECULAR STRUCTURES OF NN'-DI-ISOPROPYLDITHIO-OXAMIDE ...
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The synthesis and characterisation of a variety of SbX3L1.5 (X = Cl or Br), BiCl3L2, SnX4L (X = Cl or Br), and TiCl4L complexes i, Bun, cyclo-C6H11, or CH2Ph> is described.In all cases metal-sulphur bonds are formed following SS'-bidentate ligand attachment.The potential N-donor sites are not involved in co-ordination.The structural characterisation of the uncomplexed ligand PriNHC(S)C(S)NHPri (L3) and the antimony(III) complex SbCl3(L3)1.5 (1) are reported.Crystals of (1) are rhombohedral, space group with a = 11.80(1) Angstroem, α = 60.1(1) deg, and Z = 2. 1089 Unique data above background were collected and the structure refinded to R 0.068.Crystals of L3 are monoclinic, space group P21/c with a = 6.226(7), b = 8.067(11), c = 11.187(12) Angstroem, β = 91.0(1) deg, and Z = 2. 635 Data above background were measured and the structure refinded to R 0.077.The structure of (1) is a three-dimensional polymer.The octahedrally co-ordinated Sb atom lies on a three-fold axis and is strongly bound to three chlorine atoms and also weakly bound to three sulphur atoms from different ligands, which approach their positions trans to chlorine thus giving rise to an octahedral environment.There is no evidence for a stereochemically active lone pair associated with SbIII.In the structure of L3 the sulphur atoms are mutually trans and this orientation is retained on complexation.
- Drew, Michael G. B.,Kisenyi, Jonathan M.,Willey, Gerald R.,Wandiga, Shem O.
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p. 1717 - 1722
(2007/10/02)
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- Reactions of Cyanodithioformates with Primary Amines
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N-alkyldithiooxamides 3 and N,N-dialkyldithiooxamides 4 were synthesized in good yields by reaction of cyanodithioformates 1 with primary aliphatic amines.N-alkylcyanodithioformamides 2, intermediates in these reactions were obtained in very low yields only.The reaction of 1 and diaminoethane or 1,3-diaminopropane afforded imidazolidine-2-thione 5a respectively perhydropyrimidine-2-thione 5b.The reaction of 1 with 1-chloro-2-aminoethane did gave 2-thiocarbamoylthiazoline 7.
- Kibbel, H. U.,Kuecken, M.,Peters, E.,Weber, H.
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